Results 71 to 80 of about 28,295 (284)

High‐Performance Electrocatalysts of Potassium Lactate Oxidation for Hydrogen and Solid Potassium Acetate Production

open access: yesAdvanced Materials, Volume 37, Issue 13, April 2, 2025.
Potassium lactate, produced from polylactic acid plastic waste, is oxidized to potassium acetate on an anode using Ni(Co)OOH as the electrocatalyst, while hydrogen is simultaneously generated at the cathode, through a highly efficient industrial‐scale electrolysis system.
Jun Hu   +9 more
wiley   +1 more source

Hydroxyl-Group Identification Using O K-Edge XAFS in Porous Glass Fabricated by Hydrothermal Reaction and Low-Temperature Foaming

open access: yesMolecules, 2019
Porous glass was prepared by the hydrothermal reaction of sodium borosilicate glass, and oxygen-ion characterization was used to identify the hydroxyl groups in its surface area.
Masanori Suzuki   +3 more
doaj   +1 more source

Tuning Amorphous‐Crystalline Catalytic Interfaces by Mechanochemistry: Cu‐Based Metallic Glasses Coupled with Ceria for CO Oxidation

open access: yesAdvanced Materials, EarlyView.
Ball‐milling Cu‐based metallic glasses with ceria creates a unique nanostructure where metallic glass particles are wrapped by CeO2 nanoparticles. The intimate integration triggers copper state reorganization during reaction and aging, boosting CO oxidation and COPrOx activity.
Maahin Mirzay‐Shahim   +17 more
wiley   +1 more source

Synchrotron X-ray Absorption Spectroscopy Study of Local Structure in Al-Doped BiFeO3 Powders

open access: yesNanoscale Research Letters, 2019
The Al-doped BiFeO3, i.e., BFA x O powder samples with x = 0, 0.025, 0.05, and 0.1, were prepared via the hydrothermal route. The effects of Al substitution on the structural, electrical, and optical properties of BFA x O samples were investigated. It is
Turghunjan Gholam   +5 more
doaj   +1 more source

Evidence of magnetization-dependent polaron formation in La$_{1-x}A_x$MnO$_3$, $A$=Ca, Pb

open access: yes, 1996
X-ray-absorption fine-structure measurements at the Mn $K$-edge as a function of temperature were performed on samples of La$_{1-x}$Ca$_x$MnO$_3$ and La$_{0.67}$Pb$_{0.33}$MnO$_3$. All samples have a metal-insulator (MI) transition near the ferromagnetic
Booth, C. H.   +3 more
core   +1 more source

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

open access: yesAdvanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea   +9 more
wiley   +1 more source

Effects of Fe doping on anomalous specific heat and XAFS oscillation in antiferromagnetic metal Mn3Si

open access: yesAIP Advances, 2018
The specific heat of Mn3−xFexSi was measured over a wide temperature range. Aside from the lattice and electronic specific heat components, another component had a significant contribution to the specific heat at low temperatures in the case of x = 0.2 ...
H. Hiraka   +3 more
doaj   +1 more source

Counteranion-induced structural isomerization of phosphine-protected PdAu8 and PtAu8 clusters

open access: yesCommunications Chemistry, 2023
Controlling the geometric structures of metal clusters through structural isomerization allows for tuning of their electronic state. In this study, we successfully synthesized butterfly-motif [PdAu8(PPh3)8]2+ (PdAu8-B, B means butterfly-motif) and [PtAu8(
Yu Fujiki   +9 more
doaj   +1 more source

High-pressure study of X-ray diffuse scattering in ferroelectric perovskites

open access: yes, 2007
We present a high-pressure x-ray diffuse scattering study of the ABO$_3$ ferroelectric perovskites BaTiO_3 and KNbO_3. The well-known diffuse lines are observed in all the phases studied. In KNbO_3, we show that the lines are present up to 21.8 GPa, with
A. Gonzalo   +10 more
core   +1 more source

Polymorph‐Specific Electronic Transduction in WO3 during Molecular Sensing

open access: yesAdvanced Materials, EarlyView.
Metal‐oxide polymorphs with similar surface chemistry can nevertheless exhibit distinct sensing properties. In γ‐ and ε‐WO3, analyte adsorption appears comparable; yet, only ε‐WO3 induces a pronounced lattice electronic perturbation that accommodates charge in sub‐conduction band minimum states.
Matteo D'Andria   +6 more
wiley   +1 more source

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