Results 41 to 50 of about 7,913 (200)

Kinetic resolution of racemic {alpha}-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control [PDF]

open access: yes, 2006
Copolymerization of racemic {alpha}-olefins with ethylene and propylene was carried out in the presence of enantiopure C1-symmetric ansa metallocene, {1,2-(SiMe2)2({eta}5-C5H-3,5-(CHMe2)2)({eta}5-C5H3)}ZrCl2 to probe the effect of the polymer chain end ...
Bercaw, John E., Byers, Jeffery A.
core   +1 more source

“Naked” Divalent Metal Cations Stabilized by Weakly Coordinating Anions: Syntheses, Properties, and Emerging Applications

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The preparation of soluble and stable metal M2+ dications only stabilized by weakly coordinating anions, that is, M[WCA]2 salts, is an emerging field that, beyond its fundamental interest, holds promise in reactivity due to the high electrophilicity of the central M2+ center.
Samuel Dagorne   +3 more
wiley   +1 more source

Gas fluidized bed polymerization. [PDF]

open access: yes, 2017
Edição dos ...
GAMBETTA, R.   +2 more
core  

Electron Microscopy Transfer System to Protect Atmosphere‐Sensitive Materials for Scanning Electron Microscopy Characterization

open access: yesMicroscopy Research and Technique, EarlyView.
SEM–EDX and XRD characterization confirm that pouches made from readily available aluminum foil, used in combination with a commercial cryo‐EM transfer system, effectively protect highly atmosphere‐sensitive and/or hygroscopic materials from contamination during transfer from inert environments to the SEM vacuum chamber.
Louis G. Corcoran   +8 more
wiley   +1 more source

"Supported Ziegler-Natta catalysts from MgCl2·nROH precursors and its catalytic behaviors for diene copolymerization"

open access: yesHecheng xiangjiao gongye
The precursor MgCl2 · nROH of supported Ziegler Natta catalyst was prepared by chemical activation method, and different pre catalysts TiCl4/MgCl2 (C-Cat) were prepared by loading TiCl4.
FAN Xun-zhang, ZHAO Yuan-jin, LUO Shu-fang, HE Ai-hua?
doaj   +1 more source

Overcoming Challenges in 3D Printing of Polyolefins and Their Composites: A Review on Strategies for Improved Printability and Performance

open access: yesPolymer Engineering &Science, EarlyView.
This review integrates the molecular fundamentals, key challenges, and mitigation strategies in polyolefin 3D printing, focusing on shrinkage, warpage, and adhesion control. It highlights material design approaches using recycled polyolefins and functional fillers to improve printability, mechanical properties, and sustainability in additive ...
Malik Hassan   +5 more
wiley   +1 more source

Molecular Weight Distributions in Ideal Polymerization Reactors. An Introductory Review [PDF]

open access: yes, 2011
The ultimate aim of polymerization reaction engineering is the production of polymers with tailor-made properties. An introductory review into this field is presented, with emphasis on the effects on the molar mass distribution (MMD), of the sought ...
Meira, Gregorio Raul, Oliva, H.
core  

A mathematical model for the sequestering of chemical contaminants by magnetic particles [PDF]

open access: yes, 2010
A mathematical model is developed and implemented to characterize the pickup of various liquid chemical contaminants by polyethylene-coated magnetic particles.
Booker N. A.   +5 more
core   +1 more source

On the Bona Fide Sampling of Reaction Candidates in Red Moon Method by Replica‐Exchange Molecular Dynamics Method: REMD‐RM Method and Its Efficacy in Polymerization and Cross‐Linking Reactions of Polypropylene

open access: yesJournal of Computational Chemistry, Volume 47, Issue 7, March 15, 2026.
Schematic representation of the REMD‐RM method, which integrates the Red Moon (RM) method and the replica‐exchange molecular dynamics (REMD) method. By enhancing molecular reconfiguration and diffusion in the reactant system, the REMD‐RM method can efficiently explore a wide phase space and effectively accelerate the search for reaction candidates ...
Kentaro Matsumoto   +4 more
wiley   +1 more source

Chemical state analysis of magnesium-supported Ziegler-Natta catalyst by soft X-ray emission spectrometer (SXES) after contact with alkyl aluminum [PDF]

open access: yesPolyolefins Journal
This report is on the characterization of active Ti center in heterogeneous Ziegler-Natta catalysts with Soft X-ray Emission Spectrometer (SXES). Since titanium in the catalyst has various chemical bonds, it is important to grasp the chemical bond state.
Masayoshi Saito   +6 more
doaj   +1 more source

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