Synthesis and luminescence of 3-(pyridine-2-yl)-1,2,4-triazine-based Ir(III) complexes [PDF]
A series of novel iridium(III) complexes containing 5-N-(aryl)-amino- or 5-cycloamino-3-(pyridine-2-yl)-1,2,4-triazine ligands was obtained. These complexes exhibited red luminescence in solution as well as in the solid state.
Basim S.M. Al-Ghezi +11 more
doaj +4 more sources
6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4-triazine (1/1) [PDF]
In the title molecular salt, C5H9N4+·C13H10NO2−·C5H8N4, the asymmetric unit consists of a 6-amino-3,4-dimethyl-1,2,4-triazin-1-ium cation, a 2-anilinobenzoate anion and a neutral 3-amino-5,6-dimethyl-1,2,4-triazine molecule. The typical intramolecular N..
Ramalingam Sangeetha +3 more
doaj +2 more sources
The novel bis-1,2,4-Triazine MIPS-0004373 demonstrates rapid and potent activity against all blood stages of the malaria parasite [PDF]
Novel bis-1,2,4-triazine compounds with potent in vitro activity against Plasmodium falciparum parasites were recently identified. The bis-1,2,4-triazines represent a unique antimalarial pharmacophore and are proposed to act by a novel but as-yet-unknown
Creek, DJ +47 more
core +1 more source
Facile and Scalable Methodology for the Pyrrolo[2,1-f][1,2,4]triazine of Remdesivir [PDF]
Pyrrolo[2,1-f][1,2,4]triazine (1) is an important regulatory starting material in the production of Remdesivir (Veklury®). Compound 1 was produced through a newly developed synthetic methodology utilizing the simple building blocks pyrrole ...
Gopal, Sirasani +7 more
core +2 more sources
Hydrophilic Sulfonated Bis-1,2,4-Triazine Ligands Are Highly Effective Reagents for Separating Actinides(III) from Lanthanides(III) via Selective Formation of Aqueous Actinide Complexes [PDF]
We report the first examples of hydrophilic 6,6’-bis(1,2,4-triazin-3-yl)-2,2’-bipyridine (BTBP) and 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) ligands, and their applications as actinide(III) selective aqueous complexing agents.
Harwood, Laurence +10 more
core +1 more source
TS-BTPhen as a Promising Hydrophilic Complexing Agent for Selective Am(III) Separation by Solvent Extraction [PDF]
The novel hydrophilic back-extraction agent TS-BTPhen (3,3’,3’’,3’’’-[3-(1,10-phenanthroline-2,9-diyl)-1,2,4-triazine-5,5,6,6-tetrayl]tetrabenzenesulfonic acid) was tested for its selectivity towards Am(III) over Cm(III) and Eu(III) with a TODGA (N,N,N ...
Kaufholz, P. +15 more
core +2 more sources
1,2,4-Triazine Chemistry Part II: Synthetic approaches for phosphorus containing 1,2,4-triazine derivatives [PDF]
This review represents the methods developed for the synthesis of phosphorus containing 1,2,4-triazine moieties. These methods depends on the phosphorylation of side functional groups of 1,2,4-triazines and cyclization of side functional groups of 1,2,4 ...
Reda Mohammady Abdel-Rahman +5 more
core +1 more source
2-(3-Chloro-5,6-diphenyl-2,5-dihydro-1,2,4-triazin-5-yl)-2-methylpropanenitrile
The title compound, C19H17ClN4, was obtained from the reaction of 3-chloro-5,6-diphenyl-1,2,4-triazine with isobutyronitrile in the presence of lithium diisopropylamide as an unexpected product of covalent addition of isobutyronitrile carbanion to the C ...
Ewa Wolińska +4 more
doaj +1 more source
The separation of americium(III) from europium(III) by two new 6,6'-bistriazinyl-2,2'-bipyridines in different diluents [PDF]
The synthesis and extraction of americium(III) and europium(III) from aqueous nitric acid solutions by the new BTBP ligands 6,6’-bis(5,5,7,7- tetramethyl-5,7-dihydrofuro[3,4-e]-1,2,4-triazin-3-yl)-2,2’-bipyridine (Cy5-O-Me4-BTBP), and 6,6’-bis(5,5,7,7 ...
Petr Distler +12 more
core +1 more source
An effective and highly regio- and diastereoselective one-pot method for the synthesis of new polynuclear dispiroheterocyclic systems with five stereogenic centers (dispiro[imidazo[4,5-e]thiazolo[3,2-b]-1,2,4-triazine-6,3′-pyrrolidine-2′,3′′-indoles ...
Alexei N. Izmest’ev +9 more
doaj +1 more source

