Results 61 to 70 of about 1,432 (170)

Electrocyclic Ring‐Opening of 1,2,4‐Oxadiazole[4,5‐a]piridinium Chloride: a New Route to 1,2,4‐Oxadiazole Dienamino Compounds

open access: yesChemistryOpen, 2019
1,2,4‐Oxadiazole[4,5‐a]piridinium chloride adds nucleophiles to undergo electrocyclic ring opening affording 1,2,4‐oxadiazole dienamino derivatives. These pyridinium salts represent a special class of Zincke salts that are prone to rearrange when treated
Dr. Stefano Carella   +2 more
doaj   +1 more source

Dynamic Catalytic Highly Enantioselective 1,3-Dipolar Cycloadditions. [PDF]

open access: yesAngew Chem Int Ed Engl, 2021
Yildirim O   +5 more
europepmc   +1 more source

A Novel Cycloaddition Reaction of Thermally Generated Sulfenes

open access: yesCHIMIA, 1992
The highly strained ?-sultine 4, resulting from the addition of SO2 to benzobenzvalene, is shown to undergo a thermal cycloreversion which gives 1H-indene-1-thiocarbaldehyde dioxide (6) as an intermediate and subsequently 1H-indene-1 ...
Ulrich Burger   +3 more
doaj   +2 more sources

Acceleration of 1,3-Dipolar Cycloadditions by Integration of Strain and Electronic Tuning. [PDF]

open access: yesJ Am Chem Soc, 2021
Dones JM   +4 more
europepmc   +1 more source

Dimerization reactions of aryl selenophen-2-yl-substituted thiocarbonyl S-methanides as diradical processes: a computational study

open access: yesBeilstein Journal of Organic Chemistry, 2017
An intriguing stepwise diradical mechanism of the dimerization of the reactive intermediate (thiocarbonyl S-methanide) appearing in the reaction of phenyl selenophen-2-yl thioketone with diazomethane was studied by means of computational methods.
Michael L. McKee   +3 more
doaj   +1 more source

Multicomponent syntheses of pyrazoles via (3 + 2)-cyclocondensation and (3 + 2)-cycloaddition key steps

open access: yesBeilstein Journal of Organic Chemistry
Pyrazoles are rarely found in nature but are traditionally used in the agrochemical and pharmaceutical industries, while other areas of use are also actively developing. However, they have also found numerous other applications.
Ignaz Betcke   +3 more
doaj   +1 more source

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