1,2,4‐Oxadiazole[4,5‐a]piridinium chloride adds nucleophiles to undergo electrocyclic ring opening affording 1,2,4‐oxadiazole dienamino derivatives. These pyridinium salts represent a special class of Zincke salts that are prone to rearrange when treated
Dr. Stefano Carella +2 more
doaj +1 more source
Dynamic Catalytic Highly Enantioselective 1,3-Dipolar Cycloadditions. [PDF]
Yildirim O +5 more
europepmc +1 more source
SuFExable NH-Pyrazoles via 1,3-Dipolar Cycloadditions of Diazo Compounds with Bromoethenylsulfonyl Fluoride. [PDF]
Yamanushkin P +3 more
europepmc +1 more source
A Novel Cycloaddition Reaction of Thermally Generated Sulfenes
The highly strained ?-sultine 4, resulting from the addition of SO2 to benzobenzvalene, is shown to undergo a thermal cycloreversion which gives 1H-indene-1-thiocarbaldehyde dioxide (6) as an intermediate and subsequently 1H-indene-1 ...
Ulrich Burger +3 more
doaj +2 more sources
Acceleration of 1,3-Dipolar Cycloadditions by Integration of Strain and Electronic Tuning. [PDF]
Dones JM +4 more
europepmc +1 more source
Regio- and Diastereoselective 1,3-Dipolar Cycloadditions of 1,2,4-Triazin-1-ium Ylides: a Straightforward Synthetic Route to Polysubstituted Pyrrolo[2,1-f][1,2,4]triazines. [PDF]
Galeta J +3 more
europepmc +1 more source
An intriguing stepwise diradical mechanism of the dimerization of the reactive intermediate (thiocarbonyl S-methanide) appearing in the reaction of phenyl selenophen-2-yl thioketone with diazomethane was studied by means of computational methods.
Michael L. McKee +3 more
doaj +1 more source
Nitropyridines as 2π-Partners in 1,3-Dipolar Cycloadditions with N-Methyl Azomethine Ylide: An Easy Access to Condensed Pyrrolines. [PDF]
Bastrakov MA +3 more
europepmc +1 more source
Pyrazoles are rarely found in nature but are traditionally used in the agrochemical and pharmaceutical industries, while other areas of use are also actively developing. However, they have also found numerous other applications.
Ignaz Betcke +3 more
doaj +1 more source
Synthesis of chiral-at-metal rhodium complexes from achiral tripodal tetradentate ligands: resolution and application to enantioselective Diels-Alder and 1,3-dipolar cycloadditions. [PDF]
Tejero AG +6 more
europepmc +1 more source

