Results 11 to 20 of about 7,931 (260)

Decarboxylation-Driven Double Annulations: Innovative Multi-Component Reaction Pathways [PDF]

open access: yesMolecules
A concerted five-component reaction strategy has been developed, featuring double [3+2] cycloadditions utilizing aspartic acid. This approach provides valuable insights into mechanistic pathways, allowing for the distinction between concerted and ...
Desheng Zhan   +4 more
doaj   +2 more sources

Regiospecific 1 ,3-Dipolar Cycloaddition Polymerization of Keto-Stabilized Bisalkylidenephosphoranes with Bisazides

open access: green, 1972
Department of Chemistry, Laboratory of Macromolecular and Organic Chemistry, University of Louvain, B-3030 Heverlee, Belgium Received 4 September 1972 Thennostable poly-1,2,3-triazoles (7) were prepared by the regiospecific rt:action of bisazides with. keto-stabilhed bisalkylidenephosporanes (6) in DMSO solution.
Pierre A Ykman, G. L' ABBE, G. SMETS
openalex   +3 more sources

Stereoselective synthesis of fused tetrahydroquinazolines through one-pot double [3 + 2] dipolar cycloadditions followed by [5 + 1] annulation

open access: diamondBeilstein Journal of Organic Chemistry, 2016
The one-pot [3 + 2] cycloaddition of an azomethine ylide with a maleimide followed by another [3 + 2] cycloaddition of an azide with the second maleimide gives a 1,5-diamino intermediate which is used for a sequential aminomethylation reaction with ...
Xiaofeng Zhang   +6 more
doaj   +2 more sources

Structure, liquid and solid state synthesis for dimers via [3+3] dipolar cycloadditions [PDF]

open access: yesARKIVOC, 2005
Gheorghita N. Zbancioc   +3 more
doaj   +2 more sources

Gram Scale Synthesis of (±)-Gregatin A via 1, 3-dipolar Cycloaddition Strategy [PDF]

open access: gold
Yiming Ding   +7 more
openalex   +2 more sources

[3+2] Cycloaddition of alkyl aldehydes and alkynes enabled by photoinduced hydrogen atom transfer

open access: yesNature Communications, 2022
In contrast to the prevalence of 1,3-dipolar cycloadditions, radical [3+2] annulations of alkynes are underexplored. Here, the authors describe [3+2] cycloadditions of various internal alkynes with readily accessible aliphatic aldehydes via photoinduced ...
Siya Le   +6 more
doaj   +1 more source

Studies on the [2+3] cycloaddition reaction of nitrile oxides to abietic acid esters [PDF]

open access: yesJournal of the Serbian Chemical Society, 2019
[2+3] Dipolar cycloadditions of aromatic nitrile oxides to abietic acid esters were investigated. The reactions showed complete site selectivity and regioselectivity, while the stereoselectivity depended on the structures of the dipolarophiles.
Gucma Mirosław   +3 more
doaj   +1 more source

Reaction profiles for quantum chemistry-computed [3 + 2] cycloaddition reactions

open access: yesScientific Data, 2023
Bio-orthogonal click chemistry based on [3 + 2] dipolar cycloadditions has had a profound impact on the field of biochemistry and significant effort has been devoted to identify promising new candidate reactions for this purpose.
Thijs Stuyver   +2 more
doaj   +1 more source

Discovery of new mutually orthogonal bioorthogonal cycloaddition pairs through computational screening. [PDF]

open access: yes, 2015
Density functional theory (DFT) calculations and experiments in tandem led to discoveries of new reactivities and selectivities involving bioorthogonal sydnone cycloadditions.
Houk, KN   +3 more
core   +1 more source

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