Results 51 to 60 of about 2,717 (170)
Advances in microbial degradation of skatole: A review
In recent years, foul odors have led to widespread public complaints and have become a prominent issue in the field of environmental protection. Skatole, as one of the important components of foul odors, is a decomposition product of tryptophan in the ...
Bingjie Xu +6 more
doaj +1 more source
Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez +4 more
wiley +1 more source
A new method has been developed for the C–H formylation of aromatic compounds using silyl formates synthesized from CO2 and hydrosilanes. This is the first report on the direct C–H formylation of aromatics with silyl formates. The formylation reactions were promoted by BBr3 or BCl3. The reaction mechanism has been clarified by DFT calculations. Despite
Natsumi Nitta +5 more
wiley +1 more source
Singlet oxygen reactivity in water-rich solvent mixtures
The 3-methylindole (3MI) oxygenation sensitized by psoralen (PSO) has been investigated in 100%, 20% and 5% O2-saturated water/dioxane (H2O/Dx) mixtures. The lowering of the ¹O2* chemical rate when water (k chem∆3MI = 1.4 × 109 M-1 s-1) is replaced
Cristina Sousa +2 more
doaj +1 more source
Transplantation of Neural Stem Cells in Anosmic Mice [PDF]
ObjectivesTreating olfactory dysfunction is a challenge for physicians. One of the therapeutic options could be transplantation of stem cells. In this study, neural stem cells were transplanted into anosmic mice.MethodsNeural stem cells were generated ...
Chul Hee Lee +6 more
doaj +1 more source
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Regulation of 3‐methylindole metabolism by nuclear receptors
Regulation of 3‐methylindole metabolism by nuclear receptors 3‐methylindole (3MI) is a known pneumotoxin that is found in naturally in fecal matter and is a major component of tobacco smoke; it is also a major component of boar taint, the accumulation of malodorous compounds in pigs that negatively impacts meat quality.
Matthew A Gray, E. James Squires
openaire +1 more source
Indoles are promising N‐heterocyclic liquid organic hydrogen carriers. Here, we investigate the reaction pathways of (methyl)indole (de)hydrogenation over Pd catalysts using reaction experiments and computational modeling: we show that distinct intermediates are formed in hydrogenation versus dehydrogenation steps, and stereocenter evolution is ...
Matthew D. Edgar +6 more
wiley +1 more source
Formation Mechanisms of Odor Substances in Mutton and Deodorization Methods: A Review [PDF]
Mutton is a high-quality meat with high nutritional value. However, the typical species-specific flavor (odor) of mutton affects its quality and limits its consumer acceptance.
YANG Dongsong, GAO Shuang, YUAN Hong, ZHAO Wenxiu, LUO Yulong, LUO Ruiming, HOU Yanru
doaj +1 more source
Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa +6 more
wiley +1 more source

