Results 91 to 100 of about 100,051,810 (181)

Introduction of oxygen-functions into the alpha position of ß-diketones, 8): Acyloxylation of copper(II) acetylacetonate with diacyl peroxides. [PDF]

open access: yes, 2004
Replacement of only one hydrogen of the methylene group of 2.4-pentanedione (1) (acetylacetone) can be obtained by conversion of copper(II) acetylacetonate (2) with peroxydicarbonates 6 whereas dibenzoylperoxide (3) (DBPO) leads to geminal ...
Beck, Horst, Schank, Kurt
core   +1 more source

Occupational exposure to diacetyl and 2,3-pentanedione [PDF]

open access: yes
This criteria document is derived from the NIOSH evaluation of critical health effects studies of occupational exposure to diacetyl and 2,3-pentanedione.

core  

Nickel (II) and copper (II) complexes of tetradentate unsymmetrical Schiff base ligands: first evidence of positional isomerism in such system

open access: yes, 2006
The 1:1 condensation of 2,4-pentanedione and 1,2-diaminopropane gives a mixture two positional isomers of tridentate mono-condensed product 7-amino-4-methyl-5-aza-3-octene-2-one (HAMAO) and 7-amino-4,6-dimethyl-5-aza-3-heptene-2-one (HADAH) that reacted ...
Ray, Mau Sinha   +6 more
core   +1 more source

The Thermochemistry of Protonated and Sodiated Clusters Investigated via High-Pressure Mass Spectrometry [PDF]

open access: yes, 2007
High-pressure mass spectrometry has been employed to investigate hydrogen and sodium bound ion-molecule complexes in the gas phase. Insight into the structure and reactivity of ion-molecule complexes has been gained by examining simple mono-ketones of ...
Furzecott, Matthew
core  

Differences in odor compounds between roasted and microwaved walnut oils compared by Arrow-SPME-GC-MS combined with stoichiometry method

open access: yesShipin yu jixie
ObjectiveTo compare the effects of roasting and microwave conditions on odor compounds in walnut oil.MethodsIdentification of odor compounds in roasted walnut oil (140 ℃ roasting for 15 and 30 min; 160 ℃ roasting for 15 and 30 min) and microwaved walnut ...
XU Xiaoxue
doaj   +1 more source

Synthesis of urea derivative

open access: yes, 1990
The synthesis of a number of volatile derivative of urea has been carried out. Four pyrimidinone derivatives were chosen as targets: 4,6-dimethyl-2(1 H)-pyrimidinone, 4,6- diphenyl-2(l H) pyrimidinone, 5,5-dichloro-4,6-diphenyl-2- pyrimidinone, and 5,5 ...
Feng Cao
core  

13C and 15N NMR spectra of 6-substituted bicyclo[3,3,1]7-nonanone nitronates

open access: yes, 1984
13C and 15N NMR spectra (at the natural abundance level of 15N) have been measured and interpreted for bicyclic reaction products from 1,3,5-trinitrobenzene and cyclohexanone (I), cycloheptanone (II), cyclooctanone (III), acetone (IV), 2,4-pentanedione ...
Vladimír Macháček, Antonín Lyčka
core   +1 more source

Intramolecular hydrogen bond and proton transfer in 3-(2-benzimidazolylthio)-2,4-pentanedione. Crystallographic evidence and theoretical calculations

open access: yes, 2002
Crystal structure of the title compound is orthorhombic, Pbca, a=7.8689(2)Å, b=9.6519(3)Å, c=31.3579(9)Å. The structure was solved by direct methods and refined by a full-matrix least squares procedure to final R (all)=0.0682 for 2853 unique diffractions
Tunega, Daniel   +4 more
core   +1 more source

Metal Complexes of Aliphatic Oximes(Ⅳ)

open access: yes, 1976
2,4-pentanedione-2,4-dioxime, 2,4-pentanedione-2,3,4-trioxime의 Co(Ⅱ)착화합물의 형성조건을 검토하여 본 결과 Co(Ⅱ)착화합물은 Dioxime과 Trioxime이 pH 1~pH 4 범위에서 착화합물을 형성한다.
김상복
core   +1 more source

Elucidation of potential relationship between endogenous proteases and key flavor substances in dry-cured pork coppa

open access: yesFood Science and Human Wellness
Dry-cured meat products are considerably popular around the world due to unique flavor. Proteolysis is one of the enzymatic reactions from which flavor substances are derived, which is affected by endogenous proteases.
Mingming Li   +6 more
doaj   +1 more source

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