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Exclusive Hiyama‐Type C‐Si Arylation of Unactivated (E)‐β‐Trimethylsilyl Styrenes Catalyzed by Pd Nanoparticles in 1,3‐Dimethyl‐2‐Imidazolidinone (DMI)

open access: yesApplied Organometallic Chemistry, Volume 40, Issue 7, July 2026.
In the presence of catalytic amounts of Pd nanoparticles generated from Pd2dba3/AgBF4, (E)‐β‐trimethylsilyl styrenes undergo with aryl iodides an exclusive Hiyama‐type C‐Si coupling pathway leading to trans‐stilbenes. Side arylation products are completely eliminated if performing the reaction in 1,3‐dimethyl‐2‐imidazolidinone (DMI), an environmentally
Nikolaos Koromilas   +5 more
wiley   +1 more source

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