Results 161 to 170 of about 144,678 (301)

Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries

Angewandte Chemie, EarlyView.
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho, Al Vicente Riano D. Lisboa, Juntao Sun, Taeho Kang, Keary M. Engle   +4 more
wiley   +2 more sources

Redox State of Epigallocatechin Gallate Modulates Its Inhibition of Acrylamide Formation via the 3-Aminopropionamide Pathway. [PDF]

Foods
Qi Y, Gao M, Cheng J, Yang T, Han E, Xu B.   +5 more
europepmc   +1 more source

Concentric Rheostat Decoupled 3D Force‐Sensing Module for Smart Table Tennis Training

Advanced Intelligent Systems, EarlyView.
A 3D‐printed sensor array intrinsically decouples normal and shear forces through a unique concentric structural design. By integrating piezoresistive, sliding area‐varying capacitive, and concentric rheostat mechanisms, the 12‐sensor module achieves high‐resolution 3D force mapping without complex algorithms.
Zhe Liu, Kunlin Wu, Bingrui Sim, Wenjie Lai, Xingyu Chen, Jiajun Liu, Yifan Wang, Soo Jay Phee   +7 more
wiley   +1 more source

Substrate‐Controlled Enantiodivergence in Ni‐Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters

Angewandte Chemie, EarlyView.
An efficient, enantiodivergent synthesis of phosphorylated oxindoles with quaternary stereocenters is achieved via a nickel‐catalyzed intermolecular Heck‐phosphorylation cascade. Employing a single chiral catalyst, either product enantiomer is selectively accessed simply by changing the alkene leaving group. DFT calculations trace this stereodivergence
Haimeng Zhu, Lewen Wang, Shihui Luo, Xinglong Zhang, Jun (Joelle) Wang   +4 more
wiley   +2 more sources

Maternal Acrylamide Exposure Modulates Parvalbumin-Positive Interneurons in the Subiculum and Hippocampus of Rat Offspring. [PDF]

Biomolecules
Rycerz K, Krawczyk A, Tomaszewska E, Dobrowolski P, Muszyński S, Arciszewski MB.   +5 more
europepmc   +1 more source

Oxygen‐Tolerant Photo‐Induced Miniaturized Accelerated Atom Transfer Radical Polymerization (OPTIMA‐ATRP) for High‐Throughput Synthesis of Polymer Bioconjugates

Angewandte Chemie, EarlyView.
Oxygen‐tolerant photo‐induced miniaturized accelerated atom transfer radical polymerization (OPTIMA‐ATRP) in water was developed for the polymerization of hydrophilic (meth)acrylate monomers under ambient or sub‐ambient (4°C) temperature and atmospheric conditions, without prior degassing, in less than 10 min, at an ultra‐small scale (< 50 µL) in ...
Arman Moini Jazani, Roksana Wygoda, Hironobu Murata, Mozhdeh Madadi, Grzegorz Przesławski, Krzysztof Matyjaszewski   +5 more
wiley   +2 more sources

Association between acrylamide hemoglobin adduct levels and rheumatoid arthritis: A NHANES analysis. [PDF]

Medicine (Baltimore)
Zhang Y, Lu C, Li D, Wang C, Wu M.
europepmc   +1 more source

Auf dem Weg zu chromoselektiven Transformationen in biologischen Systemen: Perspektiven und Herausforderungen

Angewandte Chemie, EarlyView.
Die Kontrolle biologischer Systeme mit organischen Chromophoren hat sich zu einer vielversprechenden Strategie entwickelt und findet Anwendung von der chemischen Biologie bis hin zur Medizin. Die Komplexität von In‐vivo‐Systemen lässt sich jedoch nicht mit nur einer einzigen Lichtwellenlänge adäquat abbilden.
Nadja A. Simeth
wiley   +1 more source

3D‐Printable Nanoporous Thermosets via Disulfide‐Based Polymerization‐Induced Microphase Separation

Angewandte Chemie, EarlyView.
α‐Lipoic acid‐derived degradable macro‐chain transfer agents (macroCTAs) with tunable hydrophilicity drive polymerization‐induced microphase separation (PIMS) in photocurable resins. Selective etching via disulfide cleavage then generates interconnected nanoporous thermosets, and compatibility with liquid‐crystal display (LCD) 3D printing enables the ...
Xueheng Dai, Kenny Lee, Yuan Xiu, Nathaniel Corrigan, Kun Zhou, Xichuan Li, Christopher M. Bates, Craig J. Hawker, Cyrille Boyer   +8 more
wiley   +2 more sources

Is Acrylamide a Hidden Threat to Muscle Health? Integrative Evidence From Epidemiological and Mechanistic Investigations. [PDF]

Food Sci Nutr
Liu H, Yu X, Li Q, Shangguan Y, Yan L, Li H.   +5 more
europepmc   +1 more source