Dynamics and microstructures in aqueous solutions of polyacrylamide and acrylamide monomers assessed by molecular dynamics simulations combined with optical Kerr effect spectroscopy. [PDF]
RSC AdvWang L, Wang H, Sha M.
europepmc +1 more source
Functional Specialization of Respiratory and Olfactory Mucus Revealed by Proteomic Profiling
International Forum of Allergy &Rhinology, EarlyView.ABSTRACT Background Mucus overlies the nasal mucosa in the respiratory and olfactory regions, which perform distinct physiological functions. However, proteomic differences between respiratory mucosa (RM) and olfactory cleft (OC) mucus remain unclear.
Anna Kristina Hernandez +7 more
wiley +1 more source
Angewandte Chemie, EarlyView.The first hydrogel system employing anion–π interactions as a central design motif is developed. The cooperative aromatic–phosphate interaction motif provides dynamic cohesion and is proposed to regulate the separation and transport of water‐derived ionic species, achieving high piezoionic response in injectable, self‐healing, ultrasoft, low‐salinity ...
Jinyang Jiang +11 more
wiley +2 more sources
Advanced NanoBiomed Research, EarlyView.Robust attachment of hydrogels to solid substrates is critical to success in cell culture where hydrostatic and contractile forces can contribute to delamination of weakly adhered gels. This novel approach forms a nanometer‐scale, reagent‐free hydrogel primer layer to provide improved resistance to delamination of subsequent bulk hydrogel layers in a ...
Sophia C. Franklin +7 more
wiley +1 more source
Angewandte Chemie, EarlyView.Coarse‐grained (CG) molecular dynamics simulations were used to predict the upper critical solution temperature of copolymers obtained by radical ring‐opening copolymerization of cyclic ketene acetals and vinyl monomers, and to account for their unique degradation kinetics under physiological conditions by evaluating the solvation of their ester groups.
Ping Gao +3 more
wiley +2 more sources
Effect of rice flour extrusion on α-dicarbonyl compounds, protein glycation products, and the formation of acrylamide and 5-hydroxymethylfurfural in bread crust-like system. [PDF]
Food Chem XRóżańska MB, Mogol BA, Gökmen V.
europepmc +1 more source
On‐Demand Deconstructable Thermosets Through Cleavable Comonomer and Thermolatent Base Synergy
Angewandte Chemie, EarlyView.Thermosets, valued for their chemical and mechanical properties, resist recycling due to their cross‐linked structure. Weak bonds via comonomers enable degradability, but diffusion limits effectiveness. We incorporate thermolatent bases before polymerization (thermal or 3D‐VAT printing).
Sophia Kouider +15 more
wiley +2 more sources
Occurrence of Food Chemical Contaminants in Entomophagy: Implications for Food Safety and Future Risk Assessment-A Scoping Review. [PDF]
Compr Rev Food Sci Food SafEsgalhado M +9 more
europepmc +1 more source
Mechanistische Diversität in der photoangeregten Radikal‐Redoxchemie: Eine kritische Evaluierung
Angewandte Chemie, EarlyView.Für viele prominente Beispiele der Photoredox‐Katalyse wird angenommen, dass sie über die Anregung einer offenschaligen („open‐shell“) Zwischenform des Katalysators ablaufen. Es wird jedoch intensiv darüber diskutiert, ob solche Mechanismen realistisch sind und, falls ja, wie genau sie ablaufen können.
Samuel J. Horsewill +3 more
wiley +1 more source
Supramolecular Mechanophore Additives Enable Mechanochromic Hydrogels
Angewandte Chemie, EarlyView.A supramolecular loop‐forming mechanophore featuring a quencher and an emitter is incorporated as a water‐soluble macromolecular additive into hydrogels. In the stress‐free state, intramolecular charge‐transfer interactions fold the loop and quench fluorescence.
Iulia Scarlat +2 more
wiley +2 more sources