Results 181 to 190 of about 5,566 (287)

Ruthenium‐Catalyzed Nitrile‐Acrylate Reductive Coupling by 2‐Propanol: Synthesis of Enantioenriched β‐Amino Esters

Angewandte Chemie, EarlyView.
The first nitrile reductive couplings beyond stoichiometric metals or metalloids are described. Using a ruthenium catalyst derived from RuHCl(CO)(PPh3)3 and Cy‐BIPHEP, 2‐propanol‐mediated reductive coupling of phenyl acrylate with aromatic or aliphatic nitriles delivers α,β‐unsaturated β‐amino esters.
Sebastian Höthker, Colin E. Hayter, Weijia Shen, Michael J. Krische   +3 more
wiley   +2 more sources

Light-enabled metal-free carbo- and silyl functionalization of [1.1.1]propellane and [3.1.1]propellane.

Org Chem Front
Wang Y, Pauze M, Pitre SP, West JG.
europepmc   +1 more source

Accessing Molecular Complexity from Methane and Other Gaseous Alkanes via Photocatalytic Cascade Cyclization. [PDF]

Angew Chem Int Ed Engl
Nair AM, Malga JM, Martínez-Acevedo N, Fañanás-Mastral M.   +3 more
europepmc   +1 more source

Aldehyde-Olefin Couplings by Photoinduced Reduction of Electron-Deficient Olefins with Hantzsch Ester Anions. [PDF]

Angew Chem Int Ed Engl
Li Z, Noble A.
europepmc   +1 more source

Zirkuläre, Photogeschützte mRNA für Lichtinduzierte Aktivierung der Translation zu späten Zeitpunkten

Angewandte Chemie, EarlyView.
Eine klickbare, photogeschützte 5′‐Kappe (CyCliCap) zur Herstellung von zyklischer, Click‐Cap enthaltender mRNA (Cyclic Click Cap‐mRNA), die bis zur Bestrahlung beachtlich stabil und translational stumm ist, ermöglicht die Aktivierung der Translation in Zellen zu späten Zeitpunkten mittels Lichts. ZUSAMMENFASSUNG mRNA ist eine neue Impfstofftechnologie
Bayram Terzi, Greta Charlotte Dahm, Kristoffer Heintz, Martin Sumser, Yasuaki Kimura, Hiroshi Abe, Andrea Rentmeister   +6 more
wiley   +1 more source

Role of Anionic Surfactants in the Synthesis of Smart Microgels Based on Different Acrylamides

ACS Omega, 2017
Bastian Wedel, Timo Brändel, Johannes Bookhold, Thomas Hellweg   +3 more
doaj   +1 more source

Substrate-Controlled Enantiodivergence in Ni-Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters. [PDF]

Angew Chem Int Ed Engl
Zhu H, Wang L, Luo S, Zhang X, Joelle Wang J.   +4 more
europepmc   +1 more source

Encoding and Encryption via Dual‐Wavelength 3D Digital Light Processing

Angewandte Chemie International Edition, EarlyView.
Multi‐wavelength 3D DLP printing enables information encoding that can be encrypted on demand by applying orthogonal stimuli within a single material to trigger complementary responses. The 405 nm LED of the printer fabricates complex 3D geometries, while the 365 nm LED activates spiropyrans photochromism to program information into the structure ...
Finn Kröger, Michał P. Świątek, Eva Blasco   +2 more
wiley   +1 more source

Access to quaternary-carbon-containing β-alkyl amides <i>via</i> persulfate-promoted domino alkylation/smiles rearrangement of alkenes. [PDF]

RSC Adv
Yang X, Wan X, Yang WC, Fang H.
europepmc   +1 more source

Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation

Angewandte Chemie International Edition, EarlyView.
Many high‐profile examples of photoredox catalysis are proposed to proceed via excitation of an open‐shell intermediate form of the catalyst. However, there is much debate over whether such mechanisms are realistic and, if so, exactly how they can occur.
Samuel J. Horsewill, Ryan Phelps, Joshua P. Barham, Daniel J. Scott   +3 more
wiley   +1 more source