Aktivierte Thiocarbonsäureester, IV Acylierung CH-acider Thion- und Dithiocarbonsäureester / Activated Carboxylic Acid Thioesters, IV Acylation of CH-acidified Thione- and Dithiocarboxylates [PDF]
Konrad Thimm, Jürgen Voß
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The parent 5,5′‐binaphtho[2,1‐d]isoxazole and its 3,3′‐dimethyl and 3,3′‐diphenyl derivatives are synthesized via condensation of the respective dicarbonyl compounds with hydroxylamine, followed by cyclodehydration of the resulting dioximes. The dicarbonyl precursors are obtained through 4‐ or 6‐step sequences from 1‐naphthol or 1‐naphthaldehyde ...
Marek Surowiec +6 more
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Beyond Friedel-Crafts: Spontaneous and Fluoride-Catalyzed Acylation of 2-(Trialkylsilyl)pyridines. [PDF]
Dudziński J +3 more
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ZnBr2‐induced benzylation of 4‐aminopyridineswith suitable alcohols or diols provides access to novel organocatalysts of the unprecedented diarylpyrrolidionopyridine type, as well as new benzylmethylaminopyridine catalysts. These catalysts are practically inaccessible by other routes and exhibit high activity and site selectivity in the phosphorylation
Mikhail Kozlov +6 more
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Direct experimental evidence for kinetic proofreading in amino acylation of tRNAIle.
J. J. Hopfield +3 more
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Synthesis of Unnatural Aplysiatoxin Analogs with High Affinity for Protein Kinase C
In the course of synthetic study of aplysiatoxin, a potent protein kinase C (PKC) activator, it is serendipitously found that a five‐membered ether 1 obtained as an undesired product from alkyne‐containing macrodiolide 2 with Au catalyst shows a high affinity for PKC.
Mana Morishita +10 more
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Eco-friendly and efficient Friedel-Crafts acylation of activated arenes catalyzed with low-loaded ferric chloride in propylene carbonate as the solvent: scope and mechanistic insights. [PDF]
Cherif SE +5 more
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Net activity of phospholipase A2 in brain and the lack of stimulation of the phospholipase A2-acylation stem [PDF]
C. E. Rowe
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Multidrug‐resistant Klebsiella pneumoniae poses a significant threat as a nosocomial pathogen, with no current licensed vaccines available. This study used a mutant E. coli strain expressing exogenous polysaccharides (from K. pneumoniae) to establish glycoengineered generalized modules for membrane antigens (geGMMA) vaccine platform, which demonstrated
Jingqin Ye +13 more
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Selective Lysine Ubiquitination Using Activated Phenol Esters. [PDF]
Vlaming HC +9 more
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