Advanced Science, EarlyView.A Cu‐mediated Ni(OH)2 catalyst with orthogonal activity by precise valence engineering simultaneously accelerates rate‐determining aldehyde C─H activation in HMF oxidation and impedes O─H deprotonation in competing OER. This multi‐functional synergistic catalysis enables FDCA production at industrial‐level current densities without sacrificing FEFDCA ...
Junge Yang +7 more
wiley +1 more source
Photocatalytic prins-like indole addition of tryptophol C2 with aldehydes and ketones. [PDF]
RSC AdvLiu L +6 more
europepmc +1 more source
Atroposelective Construction of Axially Chiral Tetraarylethenes Via NHC‐Catalyzed Desymmetrization
Advanced Science, EarlyView.We report the first NHC‐catalyzed atroposelective synthesis of axially chiral TAEs via oxidative desymmetrization of prochiral TAE dialdehydes. This catalytic strategy operates under mild conditions and accommodates a broad range of phenolic and nitrogen nucleophiles, delivering diverse axially chiral TAEs in good yields and up to 99% ee.
Yang‐Ze Zheng +6 more
wiley +1 more source
<i>ortho</i>-Substituents govern aryl aldehyde reactivity: toward lysine-targeted, tunable inhibitors of glucose-6-phosphate dehydrogenase. [PDF]
RSC Chem BiolRowland BE +8 more
europepmc +1 more source
Nano Carbon‐mesh with Excellent Bonding Performance via Hydro‐cage De‐shielding Strategy
Advanced Science, EarlyView.A hydro‐cage de‐shielding strategy transforms cellulose‐based films into a dragonfly‐wing‐like nano carbon‐mesh (NCM) adhesive through instantaneous carbonization‐polymerization. The resulting NCM‐plywood achieves exceptional wet shear strength (1.24 MPa at 63°C), exceeding Class II plywood standards, and retains 0.73 MPa after boiling‐water cycles ...
Weijia Yang +14 more
wiley +1 more source
Noble metal-based electrocatalysts for selective alcohol oxidation to high-value chemicals: from C-C bond retention mechanism to catalyst design. [PDF]
Chem SciZhang W, Wang B, Li J, Wei Z.
europepmc +1 more source
Metal-free cascade radical cyclization of 1,6-enynes with aldehydes
, 2013 Jianyi Luo +8 more
openalex +2 more sources
Enhancing Biogenic Formic Acid Production in the Modified OxFA Process by Acetonitrile Addition
Advanced Science, EarlyView.In this study, the beneficial effect of using acetonitrile as a co‐solvent in the modified OxFA process is shown, outperforming methanol, demonstrating improved reaction kinetics combined with high selectivity for the HPA‐2 (H5PV2Mo10O40) catalyzed oxidation of xylose to FA.
Jan‐Dominik H. Krueger +7 more
wiley +1 more source
Coupling EPR spin trapping of hydroxyethyl radicals and Strecker aldehydes analysis for predicting oxidative susceptibility of Chardonnay wines. [PDF]
Curr Res Food SciHan P, Pons A.
europepmc +1 more source