Results 41 to 50 of about 12,701 (222)
Spectroscopy and Conformer‐Selective Photoelectron Circular Dichroism of Chiral Molecules
Photoelectron circular dichroism (PECD) is a forward–backward asymmetry in the angular distribution of the electrons emitted by a chiral molecule ionized by a circularly polarized light (CPL). Its sensitivity to conformation is studied by one‐photon or resonance‐enhanced two‐photon ionization, the latter being conformer‐selective.
Laurent Nahon, Anne Zehnacker
wiley +1 more source
Catalytic Conversion of Lower Olefins to Aromatics Using Zeolite‐Based Catalysts
Zeolite‐catalyzed upgrading of light olefins (C2–C4) into benzene, toluene, and xylenes (BTX) represents a sustainable route to aromatics. This review outlines thermodynamic and mechanistic aspects, the influence of acidity and textural properties of catalysts.
Paresh Butolia +5 more
wiley +1 more source
Traceless Redox-Annulations of Alicyclic Amines
Amines such as 1,2,3,4-tetrahydroisoquinoline undergo redox-neutral annulations with ortho-(nitromethyl)benzaldehyde. Benzoic acid acts as a promoter in these reactions, which involve concurrent amine α-C–H bond and N–H bond functionalization ...
Dillon R. L. Rickertsen +4 more
doaj +1 more source
This review examines bio‐based polyurethanes from renewable feedstocks, focusing on structure‐property relationships governing mechanical performance. It analyzes reinforcement strategies, benchmarks against petrochemical counterparts, and explores future directions, including non‐isocyanate routes and circular economy integration for sustainable high ...
Khaled Chawraba +4 more
wiley +1 more source
Genotypic and Phenotypic Heterogeneity in Alicyclobacillus acidoterrestris: A Contribution to Species Characterization. [PDF]
Alicyclobacillus acidoterrestris is the main cause of most spoilage problems in fruit juices and acidic products. Since soil borne species often contaminate fruit juices and do not need strict extreme requirements for survival, it is a great concern to
Bevilacqua, A +5 more
core +1 more source
Threefold reduction of 9,10,11‐triptindanetrione with LiAlH4 or NaBH4 yields exclusively the C3‐symmetric triol, suggesting an intracomplex (“rolling”) mechanism. However, use of LiAlH4/LiAlD4 (1 : 1) reveals a preceding hydride exchange. Mechanistic implications are discussed including the reduction of the related diketone.
Thorsten Hackfort +5 more
wiley +1 more source
5α-Pregna-1,20-dien-3-one
The title compound, C21H30O, was isolated from the soft coral Sinularia sp. The molecule contains four alicyclic rings, all trans-fused, among which three six-membered rings are in different distorted chair conformations while a five-membered ring ...
Guang-ying Chen +4 more
doaj +1 more source
Catalytic Hydrogenation of Lignin‐Derived Aromatics With Rhodium Oxide in Water
The easily available, easy‐to‐handle rhodium(III) oxide, Rh2O3, is shown to be a competent catalyst for arene hydrogenation, including chemoselective reduction of α,β‐unsaturated aryl ketones. Catalytic arene hydrogenation offers a direct pathway to saturated carbocycles. It can also be exploited to upgrade lignin‐derived aromatics.
Zhenyu Chen +8 more
wiley +1 more source
Cartilage‐inspired supramolecular polyurethane–urea (PU‐BAMB) elastomers are developed by integrating hierarchical hydrogen bonding and π–π stacking interactions within a dynamically reconfigurable network. This synergistic supramolecular architecture overcomes the intrinsic trade‐off between rigidity and recoverability, imparting exceptional toughness,
Rou‐Han Lai +14 more
wiley +1 more source
A study has been made of the 1 H NMR spectra of peracetylated β-glucopyranosides and α-arabinopyranosides obtained by reaction of D- and L-glucoses, and L- and D-arabinoses with either ( R )- or ( S )-2-octanols.
Tatyana N. Makarieva +8 more
doaj +1 more source

