Results 11 to 20 of about 117,983 (293)
Synthesis of a New α-Azidomethyl Styrene from Safrole via a Dearomative Rearrangement
There is a growing interest in developing more efficient synthetic alternatives for the synthesis of nitrogen-containing allylic compounds. This article presents a straightforward two-step protocol to produce 5-(3-azidoprop-1-en-2-yl)benzo[d][1,3]dioxole
Stephen R. Isbel, Alejandro Bugarin
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2-Alkylation of 3-Alkyindoles With Unactivated Alkenes
An acid-catalyzed 2-alkylation of indole molecules is developed. Only catalytic amount of the commercially available, inexpensive and traceless HI is used as the sole reaction promoter. 2,3-Disubstituted indole molecules bearing congested tertiary carbon
Xuling Pan, Qian Liu, Yingling Nong
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Asymmetric epoxidation of a series of olefinic substrates with sodium percarbonate oxidant in the presence of homogeneous catalysts based on Mn complexes with bis-amino-bis-pyridine ligands is reported.
Varvara A. Drozd +2 more
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Fischer–Tropsch synthesis (FTS) produces hundreds of hydrocarbons and oxygenates by simple reactants (CO + H2) and the detailed chain propagation mechanism is still in dispute.
Liping Zhou +4 more
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Alkene Diversification through a Molecular Recasting Strategy Enabled by <i>N</i>-Heterocyclic Carbene and Photoredox Dual Catalysis. [PDF]
Alkenes are fundamental structural motifs in organic synthesis, valued for their prevalence in natural products and their broad reactivity profile. While traditional de novo synthesis offers access to diverse alkene frameworks, strategies enabling the ...
Li QZ +6 more
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Synthetic Studies on Erythromycin Derivatives: Reactivity of the C12-21 Alkene
The reactivity of the C12-21 alkene of some erythromycin A derivatives was studied. This double bond was easily oxidized to the corresponding epoxide with excellent stereoselectivity. A single crystal X-ray structure showed that the epoxide moiety was on
Wei-Min Chen
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There is a growing need for biological and chemical methods for upcycling plastic waste streams. Pyrolysis processes can accelerate plastic depolymerization by breaking polyethylene into smaller alkene components which may be more biodegradable than the ...
Emily Byrne +3 more
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Conventional frontier molecular orbital theory is not able to satisfactorily explain the regioselectivity outcome of the nitrilimine–alkene cycloaddition.
Giorgio Molteni, Alessandro Ponti
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A mild and effective method for the conversion of alkenes into alcohols in subcritical water [PDF]
Alkenes were oxidized to alcohols in subcritical water. A number of alkenes were oxidized directly to their alcohols in excellent yields. The syntheses were performed in 215 cm3 stainless steel high pressure reactor at 120 ºC in 150 cm3 water. The yields
RECEP OZEN, NERMİN S. KUS
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Synthetic Biology Approaches to Hydrocarbon Biosensors: A Review
Monooxygenases are a class of enzymes that facilitate the bacterial degradation of alkanes and alkenes. The regulatory components associated with monooxygenases are nature’s own hydrocarbon sensors, and once functionally characterised, these components ...
Claudia F. Moratti +3 more
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