Results 21 to 30 of about 117,983 (293)
Metabolic Engineering Communications, 2018 Alkenes are industrially important platform chemicals with broad applications. In this study, we report a direct microbial biosynthesis of terminal alkenes from fermentable sugars by harnessing a P450 fatty acid (FA) decarboxylase from Macrococcus ...
Jong-Won Lee +2 more
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Science and Technology of Advanced Materials, 2019 A series of Rh-based intermetallic compounds supported on silica was prepared and tested in alkene hydrogenation at room temperature. H2 and D2 were used as the hydrogen sources and the kinetic isotope effect (KIE) in hydrogenation was studied.
Shinya Furukawa +3 more
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Frontiers in Microbiology, 2021 The ability to produce medium chain length aliphatic hydrocarbons is strictly conserved in all photosynthetic cyanobacteria, but the molecular function and biological significance of these compounds still remain poorly understood.
Eerika Vuorio +7 more
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One-pot multi-reaction processes: synthesis of natural products and drug-like scaffolds [PDF]
, 2014 One-pot multi-reaction processes involving Overman rearrangements, metathesis cyclizations, and Diels–Alder reactions have been developed for the rapid and efficient synthesis of amino-substituted carbocyclic and heterocyclic compounds.
Calder, Ewen D.D. +2 more
core +1 more source
Iodoaminations of Alkenes [PDF]
Synthesis, 2016 The activation of alkenes and their subsequent functionalization is a frequently used methodology in synthetic chemistry. This review highlights recent iodine-mediated aminations and elaborates on the various strategies to bring about regio- or stereoselective transformations.
Wirth, Thomas, Mizar, Pushpak
openaire +2 more sources
A Simple Nickel Catalyst Enabling an E‐Selective Alkyne Semihydrogenation [PDF]
, 2019 Stereoselective alkyne semihydrogenations are attractive approaches to alkenes, which are key building blocks for synthesis. With regards to the most atom economic reducing agent dihydrogen (H 2 ), only few catalysts for the challenging E ‐selective ...
Kaewmee, Benyapa +3 more
core +1 more source
An element through the looking glass: Exploring the Au-C, Au-H and Au-O energy landscape [PDF]
, 2015 Gold, the archetypal “noble metal”, used to be considered of little interest in catalysis. It is now clear that this was a misconception, and a multitude of gold-catalysed transformations has been reported.
Bochmann, Manfred +2 more
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Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation
Beilstein Journal of Organic Chemistry, 2013 Carbomagnesiation and carbozincation reactions are efficient and direct routes to prepare complex and stereodefined organomagnesium and organozinc reagents.
Kei Murakami, Hideki Yorimitsu
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Palladium-bismuth intermetallic and surface-poisoned catalysts for the semi-hydrogenation of 2-methyl-3-butyn-2-ol [PDF]
, 2015 The effects of poisoning of Pd catalysts with Bi and annealing in a polyol (ethylene glycol) were studied on the semi-hydrogenation of 2-methyl-3-butyn-2-ol (MBY).
Anderson, James A. +4 more
core +1 more source
Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes
Molecules, 1997 Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone) suppressed the reaction.
Qing-Yun Chen, Zheng-Yu Long, Ping Cao
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