A Generalized Framework for Data‐Efficient and Extrapolative Materials Discovery for Gas Separation
Advanced Intelligent Discovery, EarlyView.This study introduces an iterative supervised machine learning framework for metal‐organic framework (MOF) discovery. The approach identifies over 97% of the best performing candidates while using less than 10% of available data. It generalizes across diverse MOF databases and gas separation scenarios.
Varad Daoo, Jayant K. Singh
wiley +1 more source
Do carbenium ion additions toward alkenes proceed via .pi. complexes? A stereochemical investigation [PDF]
, 1986 Mayr, Herbert +3 more
core +1 more source
Zirconium tetrachloride-SiO2 catalyzed Knoevenagel condensation: A simple and efficient protocol for the synthesis of substituted electrophilic alkenes [PDF]
, 2008 Medamoni Vijender +2 more
openalex +1 more source
Pancake Lenses through Curved Lamination for Compact Virtual Reality
Advanced Intelligent Systems, EarlyView.This article presents an ultrathin VR optical system based on a 1.35 in. microdisplay, leveraging curved lamination technology. Compared to mainstream solutions, the proposed design demonstrates superior compactness (volume compression by 12%) and enhanced optical performance.
Jiaping Sun +5 more
wiley +1 more source
Angewandte Chemie, EarlyView.A stereospecific, transition‐metal‐free SN2 alkylation of cyanohydrins with chiral non‐racemic secondary tosylates is reported, providing efficient access to enantioenriched α‐tertiary ketones. The method exhibits broad substrate scope, operational simplicity, and excellent stereospecificity, including stereoconvergent reactions of E/Z mixtures of ...
Jinjin Ma +3 more
wiley +2 more sources
Catalyst‐Free [3+2] Cycloaddition of Isoquinolinium/Pyridinium Ylides and Electron‐Deficient Alkenes [PDF]
, 2023 Xueting Zhou +5 more
openalex +1 more source
Synthesis and Characterization of Unusual S=1 Fe(0)‐Silyl Complexes Supported by Styrene Ligands
Angewandte Chemie, EarlyView.Despite the long‐standing importance of iron‐silicon bonds as related to catalysis, high‐spin Fe(0)‐silyl complexes remain a historical synthetic challenge in the field. Herein, we report the first series of high‐spin S = 1, styrene‐stabilized Fe(0)‐silyl complexes followed by extensive characterization via Mössbauer spectroscopy, single crystal X‐ray ...
Alexis K. Bauer +2 more
wiley +2 more sources
Nickel-Catalyzed Three-Component 1,2-Carboacylation of Alkenes
MoleculesKetones, prevalent in many biologically significant molecules, require the development of novel methods to synthesize these structures, which is a critical endeavor in organic synthesis. Transition metal catalysis has proven to be an effective method for
Shengzhou Jin +4 more
doaj +1 more source
Mechanisms for the Oxonolysis of Ethene and Propene: Reliability of Quantum Chemical Predictions [PDF]
, 2003 Reactions of ozone with ethene and propene leading to primary ozonide (concerted and stepwise ozonolysis) or epoxide and singlet molecular oxygen (partial ozonolysis) are studied theoretically.
Chan, Wai-To, Hamilton, Ian P.
core +1 more source
Direct and Stereospecific [3+2] Synthesis of Pyrrolidines from Simple Unactivated Alkenes
, 2017 Jorge Otero-Fraga +4 more
openalex +2 more sources