Deuterated Cyclopropanation of Alkenes by Iron Catalysis. [PDF]
Rana IK, Nguyen KNM, Ngo DT, Nagib DA.
europepmc +1 more source
Ligand architecture and secondary‐sphere effects in a well‐defined cobalt(IV)–oxo complex
A well‐defined cobalt(IV)–oxo complex supported by a neutral tetraazamacrocyclic ligand is generated and fully characterized. The cobalt(IV)–oxo species exhibits electrophilic oxygen‐atom and hydrogen‐atom transfer reactivity, strongly modulated by protonation and secondary coordination sphere effects, providing new insight into structure–reactivity ...
Ying Xing +3 more
wiley +1 more source
Evolution of manganese low-energy photoredox catalysis from high-energy visible light photocatalysis. [PDF]
Yang W +10 more
europepmc +1 more source
This paper summarized the application of 3D bioprinting in the regeneration of various tissues in the oral and craniomaxillofacial fields, including the required biomaterials and printing techniques. Abstract Oral and craniomaxillofacial tissues are essential for maintaining oral functions, including respiration, mastication, swallowing, and speech ...
Huilu Zhan +7 more
wiley +1 more source
Cooperative NHC and Photoredox Dual Catalysis for the Construction of Carbonyl Compounds. [PDF]
Dhayalan V.
europepmc +1 more source
Atomically precise metal cluster enzymes for pathological tissue regeneration
Schematic illustration of atomically precise metal cluster enzymes (MCEs) for pathological tissue regeneration. Atomically precise MCEs can modulate biological processes, such as attenuation of inflammatory responses, eradication of bacterial pathogens, regulation of angiogenesis, and promotion of cell development.
Ziqiang Xiong +11 more
wiley +1 more source
Three-component synthesis of β-thio tertiary alkylamines from simple alkenes via S<sub>H</sub>2 homolytic substitution. [PDF]
Wang H +12 more
europepmc +1 more source
N‐formylation of dimethylamine though CO2 hydrogenation takes place at a ZnZrOx solid‐solution catalyst surface toward N,N‐dimethylformamide. By synergistic effect of Zn and Zr sites, the catalyst achieves 99% DMF selectivity at 14% DMA conversion at 280°C with at least 1000 h stability on steam.
Jinxin He +10 more
wiley +1 more source
Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes. [PDF]
Suzuki M, Nagashima Y.
europepmc +1 more source
Computational and Machine‐Learning Studies of Ethylene Oligomerization
This review focuses on recent advances in computational and machine‐learning studies of ethylene oligomerization, highlighting mainstream catalyst systems based on Co, Ta, Ti, Zr, and Hf, with particular emphasis on Fe‐ and Cr‐based catalysts and their controlling factors governing reactivity and LAO distribution.
Zhixin Qin +3 more
wiley +1 more source

