Results 201 to 210 of about 104,551 (278)

Decatungstate-photocatalyzed transfer hydrogenation of unsaturated compounds using alcohol as the hydrogen source. [PDF]

Nat Commun
Zhang T, Zhang ZF, Lan X, Li SY, Su MD, Chi YR, Wu L, So CW.   +7 more
europepmc   +1 more source

Self‐assembly and Lateral Cobalt Coordination of a Fivefold Symmetric Cyanostar Macrocycle on an Au(111) Surface

Chemistry – A European Journal, EarlyView.
Herein, we report the first example of the formation of a close‐packed, regular 2D monolayer of a fivefold symmetric cyanostar macrocycle on an Au(111) surface under ultra‐high vacuum and the structural modification of such self‐assembled architecture upon cobalt atom deposition.
Lenka Černá, Miguel Martínez García, Shanmugasibi K. Mathialagan, Sofía O. Parreiras, Koen Lauwaet, José Ignacio Urgel, Aurelio Gallardo, Amar H. Flood, Tomás Torres, José M. Gallego, Giovanni Bottari, David Écija   +11 more
wiley   +1 more source

Biomimetic sulfur-catalyzed carbonyl transfer enables the carbonylative difunctionalization of unactivated alkenes. [PDF]

Chem Sci
Wang Y, Wu XF.
europepmc   +1 more source

Harnessing Toluene Solvent as a Reactant: Regioselective Benzyl Radical Addition to Multi‐π 1,5‐Enynes in a Copper‐Catalyzed Cascade to Indenes

Chemistry – A European Journal, EarlyView.
A copper‐catalyzed three‐component radical cascade of 1,5‐enynes with toluene and benzoic acids enables regioselective benzyl radical addition to multi‐Π systems, efficiently delivering polysubstituted indenes from an abundant solvent feedstock. ABSTRACT C─H activation of toluene generates a benzyl radical that undergoes C─C coupling, converting an ...
Saideh Rajai‐Daryasarei, Fatemeh Chahardehi, Mohammad Mahdi Sharifani, Morteza Jamshidi, Robert Stranger, Frank Rominger, Alireza Ariafard, Saeed Balalaie   +7 more
wiley   +1 more source

Electroreductive Nickel-Catalyzed Intramolecular Hydrosilylation of Alkenes. [PDF]

ACS Omega
Reboli M, Durandetti M.
europepmc   +1 more source

Regio‐ and Diastereoselective C–C Silylation of Cyclopropyl Acetates Harnessing Fluorinated Poly(pyridyl)Borate Rhodium Catalysts

Chemistry – A European Journal, EarlyView.
Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan, Suman Das Adhikary, Junha Jeon, H. V. Rasika Dias   +3 more
wiley   +1 more source

Alkene Diversification through a Molecular Recasting Strategy Enabled by <i>N</i>-Heterocyclic Carbene and Photoredox Dual Catalysis. [PDF]

Research (Wash D C)
Li QZ, He MH, Wang PT, Xiang DY, Hong LH, Zeng R, Li JL.   +6 more
europepmc   +1 more source

Synthesis of 1‐Alkynylboronates, 1,1‐Diborylalkenes, and 1,1,1‐Triborylalkanes: Challenges and Opportunities

Chemistry – A European Journal, EarlyView.
ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan, Vu Nguyen Tran, Thanh Vinh Nguyen   +2 more
wiley   +1 more source

Additive-Controlled Regioswitching in Ni-Catalyzed Enantioselective Hydrophosphination of Unactivated Alkenes. [PDF]

J Am Chem Soc
Zhou J, Tao S, Zhang X, Wang J.
europepmc   +1 more source

SmI2/Sm‐Induced Reductive Silacyclization of Alkene/Diene Derivatives Using Dichlorosilanes or 1,2‐Dichlorodisilanes via Reductive Radical‐Polar Crossover

Chemistry – A European Journal, EarlyView.
A SmI2/Sm‐mediated silacyclization unlocks a concise route to 4–7‐membered silacycles from simple unsaturated substrates and dichlorosilanes/disilanes. The complementary functions of samarium reductants trigger a reductive radical–polar crossover, offering a versatile strategy for constructing multiple Si─C bonds efficiently.
Zhengwei Chen, Daigo Kondo, Tsutomu Mizota, Leo Onishi, Huiying Mu, Koji Miki, Akiya Ogawa, Kouichi Ohe   +7 more
wiley   +1 more source