Results 71 to 80 of about 104,551 (278)
Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. [PDF]
Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient ...
Jamison, Christopher R +4 more
core
Effect of zeolite topology and reactor configuration on the direct conversion of CO2 to light olefins and aromatics [PDF]
The direct transformation of CO2 into high-value-added hydrocarbons (i.e., olefins and aromatics) has the potential to make a decisive impact in our society. However, despite the efforts of the scientific community, no direct synthetic route exists today
Abou-Hamad, Edy +11 more
core +1 more source
In Situ 3D Bioprinting: Impact of Cross‐Linking on the Adhesive Properties of Hydrogels
In situ 3D bioprinting enables the direct deposition of cell‐laden, adhesive biomaterials for on‐site tissue regeneration. This review provides a comprehensive overview of how cross‐linking influences the bioadhesive properties of hydrogels used in 3D bioprinting, highlighting cross‐linking triggers, bioadhesion mechanisms, polymer interpenetration ...
Odile Romero Fernandez +4 more
wiley +1 more source
Asymmetric carbohydroxylation of alkenes offers an efficient approach to access chiral alcohols, a class of versatile building blocks in pharmaceutical and agrochemical industries, from abundant simple alkenes.
Yiyin Liu +7 more
doaj +1 more source
Cp2TiCl/D2O/Mn, a formidable reagent for the deuteration of organic compounds [PDF]
Cp2TiCl/D2O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atom transfer from D2O to different functional groups and can contribute to the synthesis of new deuterated organic compounds under friendly experimental ...
Rodríguez-García, Ignacio +1 more
core +1 more source
Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Desrat, S, van de Weghe, P
core +3 more sources
This review maps how MOFs can manage hazardous gases by combining adsorption, neutralization, and reutilization, enabling sustainable air‐pollution control. Covering chemical warfare agent simulants, SO2, NOx, NH3, H2S, and volatile organic compounds, it highlights structure‐guided strategies that boost selectivity, water tolerance, and cycling ...
Yuanmeng Tian +8 more
wiley +1 more source
Terminal epoxides undergo lithium 2,2,6,6-tetramethylpiperidide-induced α-lithiation and subsequent interception with Ph3P to provide a new and direct entry to β-lithiooxyphosphonium ylides.
David. M. Hodgson, Rosanne S. D. Persaud
doaj +1 more source
Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such
Ruizhi Guo, Lihao Liao, Xiaodan Zhao
doaj +1 more source
Anomere Amide Ermöglichen Aminative Alken‐Aryl‐ und Alken‐Alken‐Kupplungen
AbstractTrotz der Bedeutung von Kreuzkupplungsreaktionen, bei denen C−N‐Bindungen gebildet werden, stellen aminative Kupplungsansätze, bei denen zwei Fragmente direkt am Heteroatom verknüpft werden, eine selten genutzte retrosynthetische Strategie für den molekularen Aufbau dar.
Colin Stein +5 more
openaire +1 more source

