Results 71 to 80 of about 104,551 (278)

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. [PDF]

open access: yes, 2015
Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient ...
Jamison, Christopher R   +4 more
core  

Effect of zeolite topology and reactor configuration on the direct conversion of CO2 to light olefins and aromatics [PDF]

open access: yes, 2019
The direct transformation of CO2 into high-value-added hydrocarbons (i.e., olefins and aromatics) has the potential to make a decisive impact in our society. However, despite the efforts of the scientific community, no direct synthetic route exists today
Abou-Hamad, Edy   +11 more
core   +1 more source

In Situ 3D Bioprinting: Impact of Cross‐Linking on the Adhesive Properties of Hydrogels

open access: yesAdvanced Functional Materials, EarlyView.
In situ 3D bioprinting enables the direct deposition of cell‐laden, adhesive biomaterials for on‐site tissue regeneration. This review provides a comprehensive overview of how cross‐linking influences the bioadhesive properties of hydrogels used in 3D bioprinting, highlighting cross‐linking triggers, bioadhesion mechanisms, polymer interpenetration ...
Odile Romero Fernandez   +4 more
wiley   +1 more source

Asymmetric carbohydroxylation of alkenes via sequential photocatalytic oxo-alkylation and enzymatic reduction

open access: yesTetrahedron Chem
Asymmetric carbohydroxylation of alkenes offers an efficient approach to access chiral alcohols, a class of versatile building blocks in pharmaceutical and agrochemical industries, from abundant simple alkenes.
Yiyin Liu   +7 more
doaj   +1 more source

Cp2TiCl/D2O/Mn, a formidable reagent for the deuteration of organic compounds [PDF]

open access: yes, 2016
Cp2TiCl/D2O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atom transfer from D2O to different functional groups and can contribute to the synthesis of new deuterated organic compounds under friendly experimental ...
Rodríguez-García, Ignacio   +1 more
core   +1 more source

Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]

open access: yes, 2009
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Desrat, S, van de Weghe, P
core   +3 more sources

Metal–Organic Frameworks for Gaseous Pollutant Management: From Capture to Neutralization and Reutilization

open access: yesAdvanced Functional Materials, EarlyView.
This review maps how MOFs can manage hazardous gases by combining adsorption, neutralization, and reutilization, enabling sustainable air‐pollution control. Covering chemical warfare agent simulants, SO2, NOx, NH3, H2S, and volatile organic compounds, it highlights structure‐guided strategies that boost selectivity, water tolerance, and cycling ...
Yuanmeng Tian   +8 more
wiley   +1 more source

Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine

open access: yesBeilstein Journal of Organic Chemistry, 2012
Terminal epoxides undergo lithium 2,2,6,6-tetramethylpiperidide-induced α-lithiation and subsequent interception with Ph3P to provide a new and direct entry to β-lithiooxyphosphonium ylides.
David. M. Hodgson, Rosanne S. D. Persaud
doaj   +1 more source

Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants

open access: yesMolecules, 2017
A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such
Ruizhi Guo, Lihao Liao, Xiaodan Zhao
doaj   +1 more source

Anomere Amide Ermöglichen Aminative Alken‐Aryl‐ und Alken‐Alken‐Kupplungen

open access: yesAngewandte Chemie
AbstractTrotz der Bedeutung von Kreuzkupplungsreaktionen, bei denen C−N‐Bindungen gebildet werden, stellen aminative Kupplungsansätze, bei denen zwei Fragmente direkt am Heteroatom verknüpft werden, eine selten genutzte retrosynthetische Strategie für den molekularen Aufbau dar.
Colin Stein   +5 more
openaire   +1 more source

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