Results 1 to 10 of about 586,305 (334)
Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
Nature Communications, 2021 The generation of non-stabilized alkyl radicals from sulfonium salts has been a challenge for several decades. Here, the authors show the treatment of S-(alkyl) thianthrenium salts, which can generate non-stabilized alkyl radicals as key intermediates ...
Cheng Chen +4 more
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Crystals, 2021 Photoluminescent liquid crystals (PLLCs) have attracted significant attention owing to their broad applicability in thermosensing and PL switching.
Shigeyuki Yamada +10 more
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Molecules, 2023 The present work proposes the optimization of enzymatic synthesis of alkyl stearates using stearic acid, alkyl alcohols (C1-OH, C2-OH, C4-OH, C8-OH and C16-OH) and Candida rugosa lipase by a L9 (34) Taguchi-type design of experiments. Four variables were
Enoch Olvera-Ureña +5 more
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Alkylation of Dihydrofullerenes [PDF]
The Journal of Organic Chemistry, 2002 The fulleride dianions C(60)(2-) and C(70)(2-) were generated by deprotonation of the corresponding hydrogenated fullerenes, 1,2-C(60)H(2) and 1,2-C(70)H(2). These anions were prepared in the presence of a variety of alkylating agents, and mono- or dialkylated products were obtained. Alkylation was not successful with sulfonate ester alkylating agents.
Mark S. Meier +4 more
openaire +3 more sources
Nature Communications, 2023 α-Tertiary aliphatic amides are key elements in organic molecules, which are abundantly present in natural products, pharmaceuticals, agrochemicals, and functional organic materials.
Wen-Tao Zhao +3 more
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Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides
Science, 2020 Amines as a gateway to alkyl radicals In recent years, photoredox catalysis driven by blue light has often been used to oxidize carbon centers adjacent to nitrogen. Constantin et al.
Timothée Constantin +5 more
semanticscholar +1 more source
Surface mobility and structural transitions of poly(n-alkyl methacrylates) probed by dynamic contact angle measurements [PDF]
, 1986 Dynamic contact angles and contact-angle hysteresis of a series of poly(n-alkyl methacrylates) (PAMA) were investigated using the Wilhelmy plate technique.
Damme, H.S. van, Feijen, J., Hogt, A.H.
core +13 more sources
Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy
Chemical Reviews, 2020 Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl halides has a severe drawback due to the employment of toxic tin hydrides to the point that “flight from the tyranny of tin” in radical processes was ...
Stefano Crespi, M. Fagnoni
semanticscholar +1 more source
Nature Communications, 2023 Alkyl halides, widely recognized as important building blocks and reagents in organic synthesis, can serve as versatile alkyl radical precursors in radical-based transformations.
Xiang Sun, Ke Zheng
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Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling.
Angewandte Chemie, 2019 The union of photoredox and nickel catalysis has resulted in a renaissance in radical chemistry as well as in the use of nickel-catalyzed transformations, specifically for carbon-carbon bond formation.
John A. Milligan +3 more
semanticscholar +1 more source