Results 111 to 120 of about 629,880 (409)

Over 18% Efficiency from Halogen‐Free Solvent‐Processed Polymer Solar Cells Enabled by Asymmetric Small Molecule Acceptors with Fluoro‐Thienyl Extended Terminal

open access: yesAdvanced Functional Materials, EarlyView.
An asymmetric non‐fullerene acceptor BTP‐FT is developed by extending the end group of Y6‐BO with thiophene. The conformation of the molecule is determined by the noncovalent F···S interaction as demonstrated by 2D NMR and simulations. An efficiency of 18.39% is achieved in the resulting ternary solar cells processed from toluene.
Jingnan Wu   +14 more
wiley   +1 more source

Zinc Promoted Cross‐Electrophile Sulfonylation to Access Alkyl–Alkyl Sulfones

open access: yesAdvanced Science
The transition metal‐catalyzed multi‐component cross‐electrophile sulfonylation, which incorporates SO2 as a linker within organic frameworks, has proven to be a powerful, efficient, and cost‐effective means of synthesizing challenging alkyl–alkyl ...
Zhuochen Wang   +6 more
doaj   +1 more source

Evaluation of N-alkyl isatins and indoles as acetylcholinesterase and butyrylcholinesterase inhibitors

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry
Two series of N-alkyl isatins and N-alkyl indoles varying in size of the alkyl group were synthesised and evaluated for inhibition of acetylcholinesterase (AChE) and butyrylcholinesterase (BChE).
Kaitlyn N. Alcorn   +3 more
doaj   +1 more source

Theoretical kinetic study of thermal unimolecular decomposition of cyclic alkyl radicals [PDF]

open access: yesJ. Phys. Chem. A 112, 46 (2008) 11598-11610, 2009
While many studies have been reported on the reactions of aliphatic hydrocarbons, the chemistry of cyclic hydrocarbons has not been explored extensively. In the present work, a theoretical study of the gas-phase unimolecular decomposition of cyclic alkyl radicals was performed by means of quantum chemical calculations at the CBS-QB3 level of theory ...
arxiv  

The mechanism of pyridine hydrogenolysis on molybdenum-containing catalysts : IV. The conversion of piperidine [PDF]

open access: yes, 1973
The conversion of piperidine was investigated on a CoO-MoO3-Al2O3 catalysts as a function of the temperature, reaction time, initial piperidine partial pressure and the hydrogen pressure.\ud \ud At 60 atm of hydrogen and conversions below 50% piperidine ...
Mars, P., Neyens, W.J., Sonnemans, J.
core   +2 more sources

Recent Advances in Radical-Initiated C(sp3)–H Bond Oxidative Functionalization of Alkyl Nitriles

open access: yes, 2018
Chemoselective functionalizations of intrinsically less reactive C(sp3)–H bonds of alkyl nitriles are of particular interest to the chemical community because these strategies provide opportunities for the introduction of important cyanoalkyl groups onto
Xue-Qiang Chu   +3 more
semanticscholar   +1 more source

Deaminative Strategy for the Visible-Light-Mediated Generation of Alkyl Radicals.

open access: yesAngewandte Chemie, 2017
A deaminative strategy for the visible-light-mediated generation of alkyl radicals from redox-activated primary amine precursors is described. Abundant and inexpensive primary amine feedstocks, including amino acids, were converted in a single step into ...
Felix J R Klauck   +2 more
semanticscholar   +1 more source

Enhancing UV Stability and Charge Extraction in Organic Solar Cells with Phenyl‐Linked Aromatic Self‐Assembled Monolayer

open access: yesAdvanced Functional Materials, EarlyView.
The phenyl‐linked self‐assembled monolayer exhibits robust intrinsic stability and hole extraction capability compared to the alkyl‐linked counterparts, thus facilitating the device stability with T80 over 1000 h and efficiency of 19.7% in advancing organic solar cells.
Nan Zhang   +11 more
wiley   +1 more source

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation.

open access: yesJournal of the American Chemical Society, 2017
We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki-Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C ...
C. Basch   +4 more
semanticscholar   +1 more source

Hydrophobic Deep Eutectic Solvent (DES) Design Enables Optimally Hydrated DES‐in‐Water Electrolytes for High‐Performance Bromine Redox‐Enhanced Energy Storage Systems

open access: yesAdvanced Functional Materials, EarlyView.
Faradaic charging with bromine redox chemistry shows promise for energy storage, yet its efficient use in aqueous electrolytes is hindered by water decomposition and polybromides' cross‐diffusion, leading to suboptimal cell performance. This study introduces a tetrabutylammonium bromide‐based hydrated deep eutectic electrolyte with optimized water ...
Tae Pyeong Eom   +4 more
wiley   +1 more source

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