Abstract Spirocyclic compounds, particularly spirocyclohexadienones, are important in pharmaceuticals due to their biological activity. In this study, we develop a catalytic cascade oxidative spirocyclization of diarylamines for the rapid access to highly functionalized spirocyclohexadienones. Using commercially available recyclable heterogeneous metal
Kenji Matsumoto+7 more
wiley +1 more source
Unlocking the reactivity of the C-In bond: alkyl indium reagents as a source of radicals under photocatalytic conditions. [PDF]
Gladkov AA+3 more
europepmc +1 more source
Synthesis of 1-tert-Alkyl-6, 7-dimethoxyisoquinolines.
Masao Murayama
openalex +2 more sources
Continuous Flow Technology Enabling Photochemistry
The merger of continuous flow technology and modern photochemistry has enabled countless applications showcasing new opportunities for chemical synthesis demonstrating improvements in selectivity, safety, sustainability and scalability. This focused review aims to highlight a selection of recently published case studies from academic and industrial ...
Ruairi Crawford, Marcus Baumann
wiley +1 more source
Possible GABAkine-Mediated Sedative-Like Antidepressant Effects of Phytol: Molecular Interventions Through In Vitro, In Vivo and In Silico Approaches. [PDF]
Islam MT+7 more
europepmc +1 more source
CO2 in Ionene–Ionic Liquid Composite Membranes
Ionene–IL composites feature IL‐rich domains spanning hundreds of nanometers within the ionene matrix, enabling CO2 absorption and redistribution in both regions. As IL content increases, ionic domains expand, enhancing CO2 solubility. These composites offer a promising platform for CO2 separation membranes, combining improved diffusion and selectivity
Ying Chen+13 more
wiley +1 more source
Theoretical evaluation of a bulky <i>ortho</i>-thioalkyl-azobenzene as an alternative to photocontrol structural cytotoxic effects of metal-free and disulfide oxidized hSOD1 in pathogenesis of ALS. [PDF]
Galaz-Araya C+6 more
europepmc +1 more source
Second‐Generation Organic Nanozyme for Effective Detection of Agricultural Herbicides
A sustainable organic nanozyme‐based colorimetric sensing platform is developed for detecting toxic agrichemicals. The second‐generation EU nanozyme, synthesized via a modified self‐assembly process, exhibits peroxidase‐like activity, degradability, and biocompatibility.
Dong Hoon Lee, Mohammed Kamruzzaman
wiley +1 more source
Insight in the characteristics of humic substances with cotton straw derived organic materials amendments. [PDF]
Song X+7 more
europepmc +1 more source
This study shows that the n‐type doping of the P(NDI2OD‐T2) with 1H‐benzimidazoles is already effective at room temperature, leading to an increase in conductivity of more than three orders of magnitude before annealing. Spectroscopic and structural analyses, supported by DFT simulations, suggest that conformational changes in the dopant molecules upon
Simone Cimò+11 more
wiley +1 more source