Results 251 to 260 of about 480,912 (334)

Dual Photoredox/Cu‐Catalysis Enables Diastereoselective Synthesis of 3‐β‐Ethynyltropanes via Decarboxylative Alkynylation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A copper‐catalyzed decarboxylative alkynylation of tropanes is developed. This approach works under mild conditions and selectively produces a range of 3‐β‐alkynylated tropanes. Moreover, it provides a versatile and convergent platform for further functionalization of the triple bond.
Mayssa Zayene   +6 more
wiley   +1 more source

Syntheses of Thiamine Alkyl Sulfides

open access: bronze, 1956
Shun‐ichi Yamada   +2 more
openalex   +2 more sources

Impact of the Substitution Pattern in N–heterocyclic Olefin‐Substituted Phosphines on Palladium Catalysis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
The impact of olefin backbone substitution in N‐heterocyclic olefin‐substituted phosphines is investigated. While these ligands are highly electron‐donating, their catalytic activity in Pd‐catalyzed CN cross‐coupling reactions decreases as the size of the backbone substituent increases.
Nicolas Kaiser   +3 more
wiley   +1 more source

Synergistic Visible Light Nanophotocatalysis and Asymmetric Organocatalysis for the Stereoselective α‐Alkylation of Aldehydes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
An unprecedent dual catalytic nanophotocatalytic and asymmetric organocatalytic system for the α‐functionalization of aldehydes is developed using carbon nanodots as photosensitizers. The optimized methodology yields the alkylated products with up to 94% yield and up to 98:2 e.r., evidencing the possible recycling of the nanocatalysts.
Antonio Di Sabato   +9 more
wiley   +1 more source

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