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Alkyl-Dihydroxyacetonephosphate Synthase
Cell Biochemistry and Biophysics, 1997The initial steps of ether phospholipid biosynthesis take place in peroxisomes. Alkyl-dihydroxyacetonephosphate synthase, the peroxisomal enzyme that actually introduces the ether linkage, has been purified from guinea pig liver in this laboratory.
H, van den Bosch, E C, de Vet
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Alkylation‐Terminated Catellani Reactions Using Alkyl Carbagermatranes
Angewandte Chemie, 2020AbstractThe Catellani reaction has received substantial attention because it enables rapid multiple derivatization on aromatics. While using alkyl electrophiles to achieve ortho‐alkylation was one of the earliest applications of the Catellani reaction, ipso‐alkylation‐terminated reactions with β‐H‐containing reactants has not been realized to date ...
Wei‐Tao Jiang +4 more
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Bulletin du cancer, 2011
With the approval of mechlorethamine by the FDA in 1949 for the treatment of hematologic malignancies, alkylating agents are the oldest class of anticancer agents. Even though their clinical use is far beyond the use of new targeted therapies, they still occupy a major place in specific indications and sometimes represent the unique option for the ...
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With the approval of mechlorethamine by the FDA in 1949 for the treatment of hematologic malignancies, alkylating agents are the oldest class of anticancer agents. Even though their clinical use is far beyond the use of new targeted therapies, they still occupy a major place in specific indications and sometimes represent the unique option for the ...
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Alkylated steroids from tosylhydrazones and alkyl-lithiums
Journal of the Chemical Society C: Organic, 1971The reaction between 5α-cholestan-3-one tosylhydrazone and alkyl-lithium reagents produces equatorial 3β-alkyl-5α-cholestanes.
J E, Herz, C V, Ortíz
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Analysis of alkyl phosphates by extractive alkylation
Bulletin of Environmental Contamination and Toxicology, 1981The development of suitable methods for analysis of the alkyl phosphate metabolites of organophosphorus pesticides in urine has been a rather d i f f i cu l t and persistent problem. Currently available methodology (BRADWAY et al. 1977; LORES & BRADWAY 1977; SHAFIK et al. 1973) suffers from several shortcomings.
D E, Bradway, R, Moseman, R, May
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Iron‐Catalyzed Alkyl–Alkyl Suzuki–Miyaura Coupling
Angewandte Chemie International Edition, 2012Magnesium tetraalkylborates prepared from olefins, BH3·Me2S, and iPrMgCl under optimized conditions are coupled with various primary and secondary alkyl bromides to give the corresponding long-chain alkanes including fatty acid derivatives.
Takuji, Hatakeyama +5 more
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Solution properties of alkyl glucosides, alkyl thioglucosides and alkyl maltosides
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004Abstract Aqueous solutions containing sugar-based surfactants, alkyl glucosides, thioglucosides and maltosides, have been investigated in a wide concentration range, at different temperatures. Colligative properties (freezing point and vapour pressure depression), volumetric, adiabatic compressibility, surface tension and calorimetric methods were ...
Antonio Capalbi +2 more
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Enolate alkylations with alkyl halides
1997This chapter addresses enolate alkylations with alkyl halides. Simple enolates react irreversibly with soft (polarized) electrophiles such as methyl iodide. A new carbon–carbon bond is formed in an SN2, which is of considerable synthetic importance.
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