Polyphenol alkyl ester inhibits membrane cholesterol domain formation through an antioxidant mechanism based, in nonlinear fashion, on chain length [PDF]
, 2017 Under conditions of oxidative stress, cholesterol aggregates into discrete membrane bilayer domains that precipitate the formation of extracellular crystals, a hallmark feature of the advanced atheroma in cardiovascular disease.
Durand, Erwann +4 more
core +1 more source
Mechanistic Insights into Nickamine-catalyzed Alkyl-Alkyl Cross-coupling Reactions
CHIMIA, 2014 Within the last decades the transition metal-catalyzed cross-coupling of non-activated alkyl halides has significantly progressed. Within the context of alkyl-alkyl cross-coupling, first row transition metals spanning from iron, over cobalt ...
Jan Breitenfeld, Xile Hu
doaj +1 more source
Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles
Accounts of Chemical Research, 2015 Conspectus Cross-electrophile coupling, the cross-coupling of two different electrophiles, avoids the need for preformed carbon nucleophiles, but development of general methods has lagged behind cross-coupling and C–H functionalization.
D. Weix
semanticscholar +1 more source
Alkylating Agents Stronger than Alkyl Triflates [PDF]
Journal of the American Chemical Society, 2004 A new class of potent electrophilic "R(+)" alkylating agents has been developed using weakly nucleophilic carborane anions as leaving groups. These reagents, R(CHB(11)Me(5)X(6)) (R = Me, Et, and i-Pr; X = Cl, Br), are prepared via metathesis reactions with conventional alkylating agents such as alkyl triflates, using the high oxophilicity of silylium ...
Kato, Tsuyoshi +4 more
openaire +4 more sources
Novel mitochondrial-targeted alkyl chains act as fungal specific inhibitors of C. neoformans
Frontiers in MicrobiologyCryptococcus neoformans is the causal agent of cryptococcal meningitis in immunocompromised patients and increasing instances of anti-fungal resistance have led to investigations into new alternative antifungal targets. For example, C.
Elizabeth S. M. Edrich +5 more
doaj +1 more source
Particulate-bound alkyl nitrate pollution and formation mechanisms in Beijing, China [PDF]
Atmospheric Chemistry and PhysicsFine particulate matter (PM2.5) samples were collected between November 2020 and October 2021 at the Minzu University of China in Beijing, and the n-alkyl nitrate concentrations in the PM2.5 samples were determined to investigate n-alkyl nitrate ...
J. Yang +10 more
doaj +1 more source
Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates
Molecules, 2019 A direct reductive homo-coupling of alkyl tosylates has been developed by employing a combination of nickel and nucleophilic cobalt catalysts. A single-electron-transfer-type oxidative addition is a pivotal process in the well-established nickel ...
Kimihiro Komeyama +4 more
doaj +1 more source
Journal of Lipid Research, 1969 A homologous series (C10, C12, C14, C16, C18) of synthetic O-alkyl and S-alkyl ethers of glycerol was analyzed by gas-liquid chromatography (GLC) and thin-layer chromatography (TLC), and examined by IR and n.m.r.
Randall Wood +2 more
doaj +1 more source
Effect of Alkyl Side Chain Length on the Lithium-Ion Conductivity for Polyether Electrolytes
Frontiers in Chemistry, 2022 The design guidelines of polymer structure to effectively promote lithium-ion conduction within the polymer electrolytes (PEs) are crucial for its practical use.
Ryansu Sai +4 more
doaj +1 more source
Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl-Alkyl Cross-Couplings.
Journal of the American Chemical Society, 2019 A Negishi cross-coupling of alkylpyridinium salts and alkylzinc halides has been developed. This is the first example of alkyl-alkyl bond formation via cross-coupling of an alkyl amine derivative with an unactivated alkyl group, and allows both primary ...
S. Plunkett +3 more
semanticscholar +1 more source