Phosphite mediated molecular editing via switch to meta-C-H alkylation of isoquinolines: emergence of a distinct photochemical [1,3] N to C rearrangement. [PDF]
Rani S+6 more
europepmc +1 more source
Sustainable Approaches for the Protection and Deprotection of Functional Groups
Shield: Protection and deprotection are key to selective synthesis, but conventional methods can lack sustainability. This review highlights electrochemical and photochemical strategies as greener alternatives, emphasizing their mechanisms, functional group tolerance, and broad synthetic utility.
Ju Ha Jin+5 more
wiley +1 more source
Dynamically Generated Carbenium Species via Photoisomerization of Cyclic Alkenes: Mild Friedel-Crafts Alkylation. [PDF]
Schoch T+5 more
europepmc +1 more source
Mono‐ IrIII versus heterobimetallic IrIII‐AuI complexes for circularly polarized luminescence
Fundamental rationalization of the structural–circularly polarized luminescence (CPL) activity relationship is a challenging task. Herein, a pair of enantiopure, heterobimetallic IrIII–AuI complexes IrAu‐4 featuring chirality‐at‐metal is thoroughly investigated by means of spectroscopical and computational techniques, also including spin‐orbital ...
Lavinia Ballerini+9 more
wiley +1 more source
Terminal‐selective epoxidation–catalytic, simple, and with H2O2 as oxidant. The titanium complex of a new type of salan ligand, accessible in one step from cis‐DACH and 3‐(pentafluorophenyl)salicylic aldehyde, is an efficient catalyst for the epoxidation of nonconjugated olefins with H2O2.
Christina Wartmann+2 more
wiley +1 more source
Copper(I)-Catalyzed Enantioselective α-Alkylation of 2-Acylimidazoles. [PDF]
Liu ZC, Zhang HM, Li Y, Wang ZQ, Yin L.
europepmc +1 more source
We report the diversity of the photoredox reactions based on Al‐salen catalysts. The combination of an Al‐salen catalyst with an amine under visible‐light irradiation allowed the reductive transformations of aryl chlorides, carbonyl compounds, and perfluoroalkylarenes, and the oxidative transformations of amines.
Yoshihiro Nishimoto+6 more
wiley +1 more source
Development of an Adaptive, Economical, and Easy-to-Use SP3-TMT Automated Sample Preparation Workflow for Quantitative Proteomics. [PDF]
Hermanson JN, Barny LA, Plate L.
europepmc +1 more source
N,N- and N,O-Bidentate-Chelation-Assisted Alkenyl C-H Functionalization. [PDF]
Zhang Y+6 more
europepmc +1 more source
C-C bond coupling with sp3 C-H bond via active intermediates from CO2 hydrogenation. [PDF]
Ma Q+12 more
europepmc +1 more source