Results 231 to 240 of about 89,156 (285)

Sustainable Approaches for the Protection and Deprotection of Functional Groups

open access: yesChemistry – A European Journal, EarlyView.
Shield: Protection and deprotection are key to selective synthesis, but conventional methods can lack sustainability. This review highlights electrochemical and photochemical strategies as greener alternatives, emphasizing their mechanisms, functional group tolerance, and broad synthetic utility.
Ju Ha Jin   +5 more
wiley   +1 more source

Mono‐ IrIII versus heterobimetallic IrIII‐AuI complexes for circularly polarized luminescence

open access: yesChemistry – A European Journal, Accepted Article.
Fundamental rationalization of the structural–circularly polarized luminescence (CPL) activity relationship is a challenging task. Herein, a pair of enantiopure, heterobimetallic IrIII–AuI complexes IrAu‐4 featuring chirality‐at‐metal is thoroughly investigated by means of spectroscopical and computational techniques, also including spin‐orbital ...
Lavinia Ballerini   +9 more
wiley   +1 more source

Titanium cis‐DACH Salan Catalyst for the Efficient Epoxidation of Nonactivated Olefins with Hydrogen Peroxide‐Terminal‐Selective Epoxidation of Multiply Unsaturated Terpenes

open access: yesChemistry – A European Journal, EarlyView.
Terminal‐selective epoxidation–catalytic, simple, and with H2O2 as oxidant. The titanium complex of a new type of salan ligand, accessible in one step from cis‐DACH and 3‐(pentafluorophenyl)salicylic aldehyde, is an efficient catalyst for the epoxidation of nonconjugated olefins with H2O2.
Christina Wartmann   +2 more
wiley   +1 more source

A Diverse Array of Catalytic Photoredox Reactions Based on Aluminum(III)‐Salen Complexes: Understanding the Enhancement of Catalytic Activity via Amine Association

open access: yesChemistry – A European Journal, EarlyView.
We report the diversity of the photoredox reactions based on Al‐salen catalysts. The combination of an Al‐salen catalyst with an amine under visible‐light irradiation allowed the reductive transformations of aryl chlorides, carbonyl compounds, and perfluoroalkylarenes, and the oxidative transformations of amines.
Yoshihiro Nishimoto   +6 more
wiley   +1 more source

N,N- and N,O-Bidentate-Chelation-Assisted Alkenyl C-H Functionalization. [PDF]

open access: yesMolecules
Zhang Y   +6 more
europepmc   +1 more source

C-C bond coupling with sp3 C-H bond via active intermediates from CO2 hydrogenation. [PDF]

open access: yesNat Commun
Ma Q   +12 more
europepmc   +1 more source

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