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Allylic Alcohols: Ideal Radical Allylating Agents?

Accounts of Chemical Research, 2015
Radical allylations represent effective routes to various alkenes, but to date they have relied chiefly on organostannane derivatives and still suffer from significant limitations with respect to the substitution pattern of the starting allylating agent.
Debien, Laurent   +2 more
openaire   +3 more sources

Radical Allylation with α‐Branched Allyl Sulfones

Angewandte Chemie International Edition, 2008
(Chemical Equation Presented) Branching out with sulfones: The use of allyl isopropyl sulfones solves the problem of premature isomerization and allows the radical addition of xanthates to a-branched allyl sulfones (see scheme; DCE=1,2-dichloroethane, TMS=trimethylsilyl).
Charrier, Nicolas, Zard, Samir, Z.
openaire   +3 more sources

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