Facile, general allylation of unactivated alkyl halides <i>via</i> electrochemically enabled radical-polar crossover. [PDF]
Chen H, Rueping M.
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Methods for Shortening and Extending the Carbon Chain in Carbohydrates [PDF]
Monrad, Rune Nygaard
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Copper catalysis: a constantly evolving field. [PDF]
Fernández E, Yun J.
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Excited-State Palladium-Catalyzed Radical Allylic Alkylation: Rapid Access to C2-Allyl Carbohydrates. [PDF]
Yao W +5 more
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Catalytic Enantioselective C-C Coupling of Alcohols for Polyketide Total Synthesis beyond Chiral Auxiliaries and Premetalated Reagents. [PDF]
Wu J, Verboom KL, Krische MJ.
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Synthetic Studies toward the Aphidicolin Family of Diterpenoid Natural Products. [PDF]
Hayward Cooke J, Jamshed S, Sarpong R.
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B-N axis as a facilitating agent for the synthesis of 3D structures: the paradigmatic case of BN-[4.4.4]propellane. [PDF]
Sanz-Liarte G +4 more
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Allylic Alcohols: Ideal Radical Allylating Agents?
Accounts of Chemical Research, 2015Radical allylations represent effective routes to various alkenes, but to date they have relied chiefly on organostannane derivatives and still suffer from significant limitations with respect to the substitution pattern of the starting allylating agent.
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Radical Allylation with α‐Branched Allyl Sulfones
Angewandte Chemie International Edition, 2008(Chemical Equation Presented) Branching out with sulfones: The use of allyl isopropyl sulfones solves the problem of premature isomerization and allows the radical addition of xanthates to a-branched allyl sulfones (see scheme; DCE=1,2-dichloroethane, TMS=trimethylsilyl).
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