Results 61 to 70 of about 86,327 (239)

Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry : Zn–H exchange reactions and structural authentication of a dinuclear Au(I) complex with a NHC anion [PDF]

, 2013
Merging two evolving areas in synthesis, namely cooperative bimetallics and N-heterocyclic carbenes (NHCs), this study reports the isolation of the first intermediates of alkali-metal-mediated zincation (AMMZn) of a free NHC and a Zn–NHC complex using ...
Aldeco-Perez, Andrikopoulos, Arduengo, III, Arduengo, III, Armstrong, Armstrong, Armstrong, Armstrong, Arnold, Arnold, Arnold, Back, Baillie, Bantu, Bourissou, Clegg, Clegg, Clegg, Conway, Crabtree, de Frémont, Diez-Gonzalez, Flower, Furuyama, Ghadwal, Gomez-Suarez, Guisado-Barrios, Haag, Hashmi, Hashmi, Hashmi, Hashmi, Hashmi, Hashmi, Jimenez-Nunez, Kobayashi, Kronig, Linton, Masuda, Mendoza-Espinosa, Mulvey, Mulvey, Mulvey, Mulvey, Musgrave, Nobuto, Raubnheimer, Rudolph, Rudolph, Schuster, Uchiyama, Wang, Wang, Wang, Wang, Westerhausen   +55 more
core   +1 more source

Synthesis of 1‐Alkynylboronates, 1,1‐Diborylalkenes, and 1,1,1‐Triborylalkanes: Challenges and Opportunities

Chemistry – A European Journal, EarlyView.
ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan, Vu Nguyen Tran, Thanh Vinh Nguyen   +2 more
wiley   +1 more source

Teores de carboidratos em órgãos lenhosos do caquizeiro em clima tropical Carbohydrate content in persimmon tree woody organs in tropical climate

Revista Brasileira de Fruticultura, 2008
Nas fruteiras caducifólias, o metabolismo de carboidratos constitui-se no principal mecanismo que garante a sua sobrevivência no período de dormência, estando, também, relacionado ao seu potencial produtivo em safras subseqüentes. Conhecer a forma como a
Carlos Eduardo Corsato, João Alexio Scarpare Filho, Eleuza Clarete Junqueira de Sales   +2 more
doaj   +1 more source

Ca2+ binding to Chromaffin Vesicle Matrix Proteins [PDF]

, 1986
Recently we found that Ca2+ within chromaffin vesicles is largely bound [Bulenda, D., & Gratzl, M. (1985) Biochemistry 24, 7760-77651. In order to explore the nature of these bonds, we analyzed the binding of Ca2+ to the vesicle matrix proteins as well ...
Gratzl, Manfred, Reiffen, F. U.
core   +1 more source

Substituent‐Controlled Ring Opening of 1‐Substituted Benzocyclobutenes: Electronic Structure and Diradical Character of Ortho‐Quinodimethane Intermediates

Chemistry – A European Journal, EarlyView.
Experimental and computational studies elucidate how the electronic nature of substituents controls the ring‐opening temperature and diradical character of 1‐substituted benzocyclobutenes, enabling the rational design of o‐quinodimethane‐based synthetic transformations.
Magali Dallegre, Imen Abid, Roselyne Rosas, Maxime Dousset, Gaëlle Chouraqui, Laurent Commeiras, Didier Siri, Didier Gigmes, Anthony Kermagoret   +8 more
wiley   +1 more source

COMPONENTS OF CELL WALL, ENZYME ACTIVITY IN PEDICEL AND SUSCEPTIBILITY OF BANANAS TO FINGER DROP

Revista Brasileira de Fruticultura, 2016
A major problem in post-harvest handling of bananas is the individual detachment of the fruit from the hands. This study aimed to establishing the relationship between carbohydrate concentration and enzyme activity in the pedicel region of three ...
GLORIA ANNABELL COBEÑA RUIZ, LUIZ CARLOS CHAMHUM SALOMÃO, DALMO LOPES DE SIQUEIRA, SEBASTIÃO TAVARES DE REZENDE, LEILA CRISTINA ROSA DE LINS   +4 more
doaj   +1 more source

Avaliação dos grânulos de amido em plantas de mandioca (Manihot esculenta Crantz) provenientes de autofecundação. [PDF]

, 2014
O amido possui inúmeras aplicações nas indústrias de papel e celulose, petrolífera, mineração, de alimentos, farmacêutica, e outras (CARDOSO & SOUZA, 2002). A indústria modifica o amido, dando-lhe diferentes aplicações. Existe também a possibilidade de a
CAMPOS, M. C., OLIVEIRA, L. A. de, SALES, A. C., SAMPAIO FILHO, J. S., SANTOS JUNIOR, A. M. P. dos, SANTOS, V. da S.   +5 more
core  

Iridium‐Catalyzed Linear‐Selective sp3 C−H Alkylation of N‐Methylamides Using Alkenes Enabled by Diphosphite Ligands

Chemistry – A European Journal, EarlyView.
An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley   +1 more source

FONTES DE AMIDO E TEMPERATURA DE ARMAZENAMENTO NA MANUTENÇÃO DA QUALIDADE PÓS-COLHEITA DA PITAYA DE POLPA VERMELHA

Colloquium Agrariae, 2017
A pitaya é uma fruta tropical que apresenta uma perda considerável pós-colheita devido à falta de técnicas que mantenham suas propriedades qualitativas ao longo do tempo de comercialização.
Alex Guimarães Sanches, Maryelle Barros da Silva, Elaine Gleice Silva Moreira, Carlos Alberto Martins Cordeiro   +3 more
doaj   +2 more sources

Si─Si Bonding in an Unsupported N‐Heterocyclic Silylene Dimer Stabilized by an Iminophosphorane‐Based Scorpionate Ligand Versus Head‐to‐Tail Coordination in the Sn and Pb Tetrylenes

Chemistry – A European Journal, EarlyView.
A new iminophosphorane‐based scorpionate ligand enabled the characterization of a head‐to‐head silylene dimer with unsupported Si─Si bonding, whereas the tetrylene species of Sn and Pb afforded head‐to‐tail coordination polymers in the solid state. ABSTRACT N,N‐chelating ligands disfavor element–element bonding in heavier alkene analogs of group 13 and
Huanhuan Dong, Rochelle Ferns, Luke W. Giles, Lea Fohlmeister, Connor Bourne, Samuel R. Lawrence, Aidan P. McKay, Alexandra M. Z. Slawin, David B. Cordes, Tanja van Mourik, Andreas Stasch   +10 more
wiley   +1 more source