Results 71 to 80 of about 86,327 (239)

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Investigação dos processos de gelatinização e extrusão de amido de milho

open access: yesPolímeros, 2000
Os processos de gelatinização e de extrusão de amido de milho foram estudados. Calorimetria diferencial de varredura e miscroscopia óptica foram utilizadas na determinação da temperatura de gelatinização, T(G), em função do grau de umidade.
Souza Roberta C. R., Andrade Cristina T.
doaj  

Aclimatação de gengibre (Zingiber officinale Roscoe) e a relação com carboidratos endógenos Acclimation of ginger (Zingiber officinale Roscoe) and its relation to endogenous carbohydrates

open access: yesRevista Brasileira de Plantas Medicinais, 2010
O objetivo deste trabalho foi determinar as variações dos teores de açúcares solúveis totais e de reserva nas diferentes fases de desenvolvimento de mudas de gengibre.
C.G Girardi, R Pescador
doaj   +1 more source

Scope and Mechanistic Study of the Ruthenium-Catalyzed \u3cem\u3eortho\u3c/em\u3e-C−H Bond Activation and Cyclization Reactions of Arylamines with Terminal Alkynes [PDF]

open access: yes, 2005
The cationic ruthenium hydride complex [(PCy3)2(CO)(CH3CN)2RuH]+BF4- was found to be a highly effective catalyst for the C−H bond activation reaction of arylamines and terminal alkynes.
Yi, Chae S., Yun, Young
core   +1 more source

Heuristics-Guided Exploration of Reaction Mechanisms

open access: yes, 2015
For the investigation of chemical reaction networks, the efficient and accurate determination of all relevant intermediates and elementary reactions is mandatory.
Bergeler, Maike   +3 more
core   +3 more sources

Bimetallic Cooperativity in Proton Reduction with an Amido‐Bridged Cobalt Catalyst [PDF]

open access: yes, 2017
The bimetallic catalyst [CoII2(L1)(bpy)2]ClO4 (1), in which L1 is an [NN′2O2] fused ligand, efficiently reduced H+ to H2 in CH3CN in the presence of 100 equiv of HOAc with a turnover number of 18 and a Faradaic efficiency of 94 % after 3 h of bulk ...
Fiedler, Adam T.   +5 more
core   +2 more sources

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source

A New Colorimetric Assay for Methionyl Aminopeptidases: Examination of the Binding of a New Class of Pseudopeptide Analog Inhibitors [PDF]

open access: yes, 2006
A direct and convenient spectrophotometric assay has been developed for methionine aminopeptidases (MetAPs). The method employs the hydrolysis of a substrate that is a methionyl analogue of p-nitroaniline (l-Met-p-NA), which releases the chromogenic ...
Dygas-Holz, Anna M.   +5 more
core   +2 more sources

Mechanistic Paths for the Gold(I)‐Catalyzed Heteroannulation of Salicylic Amides With Apolar Alkynes Explored With Density Functional Theory Calculations

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A manifold of catalytic reaction paths can operate in the Au(I)‐catalyzed heteroannulation of salicylic amides and alkynes. However, a subtle initial nucleophilic advantage of N versus O and a kinetic bottleneck at an advanced stage of the mechanistic machinery seems to suffice for the reaction to run on a single path and with exquisite selectivity. We
Ioannis Stylianakis   +3 more
wiley   +1 more source

Amido resistente: características físico-químicas, propriedades fisiológicas e metodologias de quantificação

open access: yesCiência Rural, 2005
Encontrado em diversos alimentos, o amido é a mais importante fonte de carboidratos da dieta. Potencialmente digerível pelas enzimas no trato gastrintestinal, é absorvido na forma de glicose no intestino delgado. Apesar disso, quantidade significativa de
Walter Melissa   +2 more
doaj  

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