Results 21 to 30 of about 44,767 (191)

Electrospinning and Post-Spun Chain Conformations of Synthetic, Hydrophobic Poly(α-amino acid)s. [PDF]

open access: yes, 2020
Electrospinning and post-spun conformations of hydrophobic poly(α-amino acid)s are described in this study. The poly(α-amino acid)s, poly(Gly), poly(L-Ala), poly(L-Val), and poly(L-Leu) were synthesized via corresponding N-carboxy-a-amino acid anhydrides.
Devarayan, Kesavan   +4 more
core   +1 more source

Ionic Clusters vs Shear Viscosity in Aqueous Amino Acid Ionic Liquids [PDF]

open access: yesThe Journal of Physical Chemistry B, 2015
Aqueous solutions of amino acid ionic liquids (AAILs) are of high importance for applications in protein synthesis and solubilization, enzymatic reactions, templates for synthetic study, etc. This work employs molecular dynamics simulations using our own force field to investigate shear viscosity and cluster compositions of three 1-ethyl-3 ...
Chaban, Vitaly V., Fileti, Eudes Eterno
openaire   +3 more sources

Synthesis and Physico-Chemical Properties of New Tetraethylammonium-Based Amino Acid Chiral Ionic Liquids

open access: yesMolecules, 2010
This paper reports the synthesis of a series of new tetraethylammonium-based amino acid chiral ionic liquids (CILs). Their physico-chemical properties, including melting point, thermal stability, viscosity and ionic conductivity, have been ...
Mohd Basyaruddin Abdul Rahman   +5 more
doaj   +1 more source

Hydrogen bonding as a clustering agent in protic ionic liquids: like-charge vs opposite-charge dimer formation [PDF]

open access: yes, 2018
The local structure of a series of homologous protic ionic liquids (PILs) is investigated using ab initio computations and ab initio-based molecular dynamics. The purpose of this work is to show that in PILs the network of hydrogen bonds may promote like-
Adenusi, Henry   +3 more
core   +3 more sources

Specification of Zwitterionic or Non-Zwitterionic Structures of Amphoteric Compounds by Using Ionic Liquids

open access: yesActa Chimica Slovenica, 2020
Some imidazolium-based ionic liquids were used to determine zwitterionic or non-zwitterionic structures of glycine and p-amino benzoic acid, as model amphoteric compounds, in their corresponding isoelectric point.
Leila Sheikhian   +2 more
doaj   +1 more source

A Computational Analysis of the Reaction of SO2 with Amino Acid Anions: Implications for Its Chemisorption in Biobased Ionic Liquids

open access: yesMolecules, 2022
We report a series of calculations to elucidate one possible mechanism of SO2 chemisorption in amino acid-based ionic liquids. Such systems have been successfully exploited as CO2 absorbents and, since SO2 is also a by-product of fossil fuels’ combustion,
Vanessa Piacentini   +3 more
doaj   +1 more source

Quantification of amino acids and peptides in an ionic liquid based aqueous two-phase system by LC–MS analysis

open access: yesAMB Express, 2018
Aqueous two-phase systems (ATPS) occur by the mixture of two polymers or a polymer and an inorganic salt in water. It was shown that not only polymers but also ionic liquids in combination with inorganic cosmotrophic salts are able to build ATPS ...
Sebastian Oppermann   +5 more
doaj   +1 more source

Mechanisms of CO2 Capture in Ionic Liquids: A Computational Perspective [PDF]

open access: yes, 2016
We present computational studies of CO2 sorption in two different classes of ionic liquid. The addition of carbon dioxide to four superbase ionic liquids, [P3333][Benzim], [P3333][124Triz], [P3333][123Triz] and [P3333][Bentriz] was studied using DFT ...
Bell, RG, de Leeuw, NH, Mercy, M
core   +2 more sources

Two-Dimensional Controlled Syntheses of Polypeptide Molecular Brushes via N-Carboxyanhydride Ring-Opening Polymerization and Ring-Opening Metathesis Polymerization. [PDF]

open access: yes, 2017
Well-defined molecular brushes bearing polypeptides as side chains were prepared by a "grafting through" synthetic strategy with two-dimensional control over the brush molecular architectures.
Borguet, Yannick P   +7 more
core   +1 more source

A Systematic Review of Amino Acid-Based Adsorbents for CO2 Capture

open access: yesEnergies, 2022
The rise of carbon dioxide (CO2) levels in the atmosphere emphasises the need for improving the current carbon capture and storage (CCS) technology. A conventional absorption method that utilises amine-based solvent is known to cause corrosion to process
Nur Syahirah Mohamed Hatta   +3 more
doaj   +1 more source

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