Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation
From redox numbers to red light: Donor oxidation and core reduction potentials predict E0‐0 in cyanoarene dyes, guiding selection of an efficient red‐light catalyst, 4MeODPATPN (PC13). Under 620 nm light, PC13 facilitates Ni‐catalyzed C─heteroatom cross‐couplings (C─N, C─O, C─S) with high functional‐group tolerance and reduced hydrodehalogenation ...
Amir Gizatullin +6 more
wiley +2 more sources
Redox-Amino Acid Metabolic Crosstalk in Ovarian Cancer Stem Cells: Integrating Metabolic Reprogramming, Signaling, and the Tumor Microenvironment. [PDF]
Liu D, Yi H, Yi C.
europepmc +1 more source
Precise modulation of Fe–N4 site distances constructs spin‐regulated Fe–N4 twins, triggering a volcano‐type Fenton‐like activity and promoting oriented singlet oxygen generation. The twin‐site catalyst enables highly selective and efficient hospital wastewater purification with simultaneous pharmaceutical degradation and disinfection under low ...
Xinhao Wang +10 more
wiley +2 more sources
DFT calculations do not explain enantiospecific NMR responses in cross polarization. [PDF]
Ketzel AF +4 more
europepmc +1 more source
Metabolomics after trauma in experimental models- a systematic review. [PDF]
Stückelberger G +7 more
europepmc +1 more source
A new LUCApedia database for data-driven research on early evolutionary history. [PDF]
Nikfarjam Z +4 more
europepmc +1 more source
Contact Electrification-Based Enantioselective Recognition of Chiral Amino Acids through Stereospecific Interfacial Electron Transfer. [PDF]
Pal A +6 more
europepmc +1 more source
Early-Life Hydrogen Sulfide Signaling as a Target for Cardiovascular-Kidney-Metabolic Syndrome Reprogramming. [PDF]
Hsu CN +4 more
europepmc +1 more source
Unraveling the Role of the Multifunctional Groups in the Adsorption of l-Cysteine on Rutile TiO<sub>2</sub>(110). [PDF]
Blanco Garcia M +10 more
europepmc +1 more source
Metabolic profiles of amino acids in patients with crohn's disease-associated perianal fistulas and cryptoglandular anal fistulas. [PDF]
Ma K +6 more
europepmc +1 more source

