Results 151 to 160 of about 597,754 (265)

Anomeric Amide Enabled Divergent Synthesis of Unsymmetrical Ureas, Carbamates, Thioesters, and Amides From Aldehydes

open access: yesAngewandte Chemie International Edition, EarlyView.
An anomeric amide‐enabled divergent aldehyde functionalization sequence provides one‐pot access to unsymmetrical ureas, carbamates, thiocarbamates, thioesters, and amides. Key to this transformation is the formation of N‐Boc‐hydroxamate intermediates, which serve as platforms for orthogonal activation via Lossen‐type rearrangements, single‐electron ...
Jasper L. Tyler   +6 more
wiley   +1 more source

Context-Dependent Chemoselectivity of Aromatic C-Methyltransferases. [PDF]

open access: yesChembiochem
Breiltgens J   +4 more
europepmc   +1 more source

Catalytic C–F Bond Activation at Room Temperature: Enolate Cross‐Couplings Enabled by [Pd(1‐MeNAP)TFA]2 and LiHMDS

open access: yesAngewandte Chemie International Edition, EarlyView.
Catalysts generated from the trifluoroacetate‐bridged methylnaphthyl‐palladium dimer [Pd(1‐MeNAP)TFA]2 and biarylphosphine ligands in combination with the base LiHMDS promote α‐arylation reactions of various enolates with non‐activated aryl fluorides at room temperature.
Nele Krüger   +4 more
wiley   +1 more source

Deoxyradiofluorination of Phenols via a Difluoromethoxy Nucleofuge Enabled by Organic Photoredox Catalysis. [PDF]

open access: yesACS Cent Sci
Mungalpara MN   +12 more
europepmc   +1 more source

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