Shape-Conserving Atom Replacements. [PDF]
Puriņš M, Elgindy C, Levin MD.
europepmc +1 more source
Controlled Triazine-Based Covalent Functionalization of Black Phosphorus for Degradable Hybrid Materials. [PDF]
Er J +18 more
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A mechanochemical route to triazatrinaphthylenes: building blocks for π-extended, nitrogen-enriched two-dimensional metal-organic frameworks. [PDF]
Mahapatra R +3 more
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Ambiphilic behavior of hydrogen in trisubstituted silanes induced by substituent controlled polarity inversion. [PDF]
Hrubý V, Manna D, Lo R, Hobza P.
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Concerted Nucleophilic Aromatic Substitution Reactions [PDF]
AbstractRecent developments in experimental and computational chemistry have identified a rapidly growing class of nucleophilic aromatic substitutions that proceed by concerted (cSNAr) rather than classical, two‐step, SNAr mechanisms. Whereas traditional SNAr reactions require substantial activation of the aromatic ring by electron‐withdrawing ...
Darren Poole +2 more
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Dehalogenation of Aromatics by Nucleophilic Aromatic Substitution
Nucleophilic aromatic substitution has been implicated as a mechanism for both the biotic and abiotic hydrodehalogenation of aromatics. Two mechanisms for the aqueous dehalogenation of aromatics involving nucleophilic aromatic substitution with hydride as a nucleophile are investigated using a validated density functional and continuum solvation ...
Christopher J Cramer +1 more
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Aromatic Nucleophilic Substitution Reactions.
Chemical Reviews, 1951Joseph F Bunnett
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On the Frontier Between Nucleophilic Aromatic Substitution and Catalysis [PDF]
AbstractA study on the arylation of heteroatom nucleophiles by using activated haloarenes, with or without metal catalysts, is reported. A discussion concerning the involvement of traces of metals is presented, supported by an unexpected ''ligand'' effect in the absence of added metal catalysts.
Thierry Ollevier, Marc Taillefer
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ChemInform Abstract: Nucleophilic Aromatic Substitutions
ChemInform, 1981AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
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Nucleophilic aromatic substitution on aromatic aldimines
Tetrahedron Letters, 1993Abstract Ortho-methoxy-substituted benzaldimines derived from 3-amino-2,4-dimethylpentane undergo efficient nucleophilic aromatic substitution with typical organolithium reagents. The aldimine products can be hydrolyzed under mild conditions to provide ortho-alkyl or ortho-phenyl benzaldehyde derivatives.
Lec A. Flippin +2 more
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