Results 201 to 210 of about 597,754 (265)

Selective Electrochemical Defluorinative Hydroxymethylation toward Difluoro-Substituted Alcohol Building Blocks. [PDF]

Org Lett
Shatskiy A, Holczer M, Winter J, Fan Z, Breitwieser K, Lundberg H.   +5 more
europepmc   +1 more source

Rapid Access to Photoswitchable RNA Binders: Fluorination Enhances Protein Rescue by Exon Inclusion

Chemistry – A European Journal, EarlyView.
An adaptable approach, many light‐switchable RNA binders. We report a versatile strategy for rapidly synthesizing photoswitchable RNA binders. The ligands can target SMN2 pre‐mRNA, restoring the levels of the corresponding protein by exon‐inclusion rescue.
Lei Zhang, Nemanja Djokovic, Alexander Herr, Anna Wacker, Emily Swanson Hay, Daniel Santana, Amanda E. Hargrove, Harald Schwalbe, Katarina Nikolic, Frank Abendroth, Olalla Vázquez   +10 more
wiley   +1 more source

Conjugated Nitroolefins as Twofold Electrophiles for the Assembly of Five-Membered Monoheterocycles via MIRC [3+2] Annulation: An Update on Synthetic and Mechanistic Aspects. [PDF]

Molecules
Bianchi L, Maccagno M, Petrillo G, Tavani C.   +3 more
europepmc   +1 more source

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

Chemistry – A European Journal, EarlyView.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua, Alberto Luridiana, Francesco Secci, Emanuele Cocco   +3 more
wiley   +1 more source

Discovering CO₂-Reactive Carbanions via Property-Guided Generative AI. [PDF]

J Chem Inf Model
Li B, Jiang DE.
europepmc   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

Chemistry – A European Journal, EarlyView.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik, Borys B. Palianytsia, Mykola M. Ilchenko, Nataliia S. Nastasiienko, David J. Morgan, Liudmila P. Storozhuk, David J. Willock, Greg Shaw, Duncan F. Wass, Rafael Luque, Philip R. Davies, Mykola T. Kartel   +11 more
wiley   +1 more source

Synthetic Studies Towards Darobactin A. [PDF]

Chemistry
Steiner T, Versini A, Schellenberg M, Schuler E, Gademann K.   +4 more
europepmc   +1 more source

New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experimental and Theoretical Study

Chemistry – A European Journal, EarlyView.
Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient‐temperature polymerization through chloride‐catalyzed cationic pathways involving dissociation, nucleophilic chloride attack, and chain‐propagating species formation ...
Cornelius Knuth, Paul Strasser, Carmen Hoth, Joerg Harloff, Thomas Eickner, Ian Teasdale, Axel Schulz   +6 more
wiley   +1 more source

Synthesis of Csp ³ Chlorinated Compounds from Cyclopropanes, Olefins, and C-H Bonds via Photolysis of Willgerodt-Type Reagents. [PDF]

JACS Au
Nguyen TVT, Nguyen TVQ, Tran TTH, Nguyen QH, Waser J.   +4 more
europepmc   +1 more source

Structural and mechanistic insights into the divergence of pterin deaminase and sepiapterin deaminase. [PDF]

Appl Microbiol Biotechnol
Shanmuganathan N, Manikandan S, Johnson J, Balasubramani S, Jayaraman A, Paleri S, Ranjith T, A TP.   +7 more
europepmc   +1 more source