Results 1 to 10 of about 178,280 (167)

SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA [PDF]

open access: yesمجلة جامعة الانبار للعلوم الصرفة, 2012
This research concerned with the reaction of Aryl- benzoylchloride with 1,3-cyclohexanedione in aqueous media (which has been catalyzed by p-dodecylbenezenesulfonic acid (DBSA) or sodiumdodecylsulfate (SDS)).
MARWAN M. F. AL-HEETY
doaj   +1 more source

Replacing “Alkyl” with “Aryl” for inducing accessible channels to closed pores as plateau‐dominated sodium‐ion battery anode

open access: yesSusMat, 2022
Hard carbons are promising anodes for sodium‐ion batteries. However, there is still considerable controversy regarding the sodium storage behaviors in hard carbons, which are mainly attributed to the varied precursors, confused pyrolysis mechanism, and ...
Wenlong Shao   +8 more
doaj   +1 more source

Computational insights into electrochemical cross‐coupling of quaternary borate salts

open access: yesElectrochemical Science Advances, 2022
Cross‐coupling reactions for C–C bond formation represent a cornerstone of organic synthesis. In most cases, they make use of transition metals, which has several downsides.
Florian Matz   +3 more
doaj   +1 more source

Aryl acrylonitriles synthesis enabled by palladium-catalyzed α-alkenylation of arylacetonitriles with vinyl halides/triflates

open access: yesFrontiers in Chemistry, 2022
Aryl acrylonitriles are an important subclass of acrylonitriles in the medicinal chemistry and pharmaceutical industry. Herein, an efficient synthesis of aryl acrylonitrile derivatives using a Palladium/NIXANTPHOS-based catalyst system was developed ...
Yonggang Jiang   +7 more
doaj   +1 more source

One-Pot Iridium Catalyzed C–H Borylation/Sonogashira Cross-Coupling: Access to Borylated Aryl Alkynes

open access: yesMolecules, 2020
Borylated aryl alkynes have been synthesized via one-pot iridium catalyzed C–H borylation (CHB)/Sonogashira cross-coupling of aryl bromides. Direct borylation of aryl alkynes encountered problems related to the reactivity of the alkyne under CHB ...
Ghayoor A. Chotana   +4 more
doaj   +1 more source

Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C–O bond cleavage

open access: yesNature Communications, 2023
Although aryl triflates are essential building blocks in organic synthesis, the applications as aryl radical precursors are limited. Herein, we report an organomediated electrochemical strategy for the generation of aryl radicals from aryl triflates ...
Xianqiang Kong   +8 more
doaj   +1 more source

Enantiomer stability of atropisomeric 1,5-disubstituted 1,2,3-triazoles

open access: yesTetrahedron Chem, 2022
The synthesis and characterisation of axially chiral atropisomeric 1,5-disubstituted 1,2,3-triazoles is reported. Molecules designed to display restricted rotation about 1,2,3-triazole N-1-aryl or 1,2,3-triazole C-5-aryl bonds were investigated by ...
Fernanda Meloni   +6 more
doaj   +1 more source

Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals

open access: yesMolecules, 2022
Aryl- and heteroaryl units are present in a wide variety of natural products, pharmaceuticals, and functional materials. The method for reduction of aryl halides with ubiquitous distribution is highly sought after for late-stage construction of various ...
Jihong Lan   +4 more
doaj   +1 more source

Cu-Catalyzed Arylation of Bromo-Difluoro-Acetamides by Aryl Boronic Acids, Aryl Trialkoxysilanes and Dimethyl-Aryl-Sulfonium Salts: New Entries to Aromatic Amides

open access: yesMolecules, 2021
We describe a mechanism-guided discovery of a synthetic methodology that enables the preparation of aromatic amides from 2-bromo-2,2-difluoroacetamides utilizing a copper-catalyzed direct arylation.
Satenik Mkrtchyan   +4 more
doaj   +1 more source

Synthesis of 2-aryl-benzothiazoles via Ni-catalyzed coupling of benzothiazoles and aryl sulfamates

open access: yesHeterocyclic Communications, 2020
2-Aryl-benzothiazoles have been successfully synthesized via a simple coupling reaction between benzothiazoles and aryl sulfamates using a nickel catalyst. The nickel catalyst is inexpensive, reusable and commercially available.
Yu Xiaofeng   +4 more
doaj   +1 more source

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