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SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA [PDF]
This research concerned with the reaction of Aryl- benzoylchloride with 1,3-cyclohexanedione in aqueous media (which has been catalyzed by p-dodecylbenezenesulfonic acid (DBSA) or sodiumdodecylsulfate (SDS)).
MARWAN M. F. AL-HEETY
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Hard carbons are promising anodes for sodium‐ion batteries. However, there is still considerable controversy regarding the sodium storage behaviors in hard carbons, which are mainly attributed to the varied precursors, confused pyrolysis mechanism, and ...
Wenlong Shao +8 more
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Computational insights into electrochemical cross‐coupling of quaternary borate salts
Cross‐coupling reactions for C–C bond formation represent a cornerstone of organic synthesis. In most cases, they make use of transition metals, which has several downsides.
Florian Matz +3 more
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Aryl acrylonitriles are an important subclass of acrylonitriles in the medicinal chemistry and pharmaceutical industry. Herein, an efficient synthesis of aryl acrylonitrile derivatives using a Palladium/NIXANTPHOS-based catalyst system was developed ...
Yonggang Jiang +7 more
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Borylated aryl alkynes have been synthesized via one-pot iridium catalyzed C–H borylation (CHB)/Sonogashira cross-coupling of aryl bromides. Direct borylation of aryl alkynes encountered problems related to the reactivity of the alkyne under CHB ...
Ghayoor A. Chotana +4 more
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Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C–O bond cleavage
Although aryl triflates are essential building blocks in organic synthesis, the applications as aryl radical precursors are limited. Herein, we report an organomediated electrochemical strategy for the generation of aryl radicals from aryl triflates ...
Xianqiang Kong +8 more
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Enantiomer stability of atropisomeric 1,5-disubstituted 1,2,3-triazoles
The synthesis and characterisation of axially chiral atropisomeric 1,5-disubstituted 1,2,3-triazoles is reported. Molecules designed to display restricted rotation about 1,2,3-triazole N-1-aryl or 1,2,3-triazole C-5-aryl bonds were investigated by ...
Fernanda Meloni +6 more
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Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
Aryl- and heteroaryl units are present in a wide variety of natural products, pharmaceuticals, and functional materials. The method for reduction of aryl halides with ubiquitous distribution is highly sought after for late-stage construction of various ...
Jihong Lan +4 more
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We describe a mechanism-guided discovery of a synthetic methodology that enables the preparation of aromatic amides from 2-bromo-2,2-difluoroacetamides utilizing a copper-catalyzed direct arylation.
Satenik Mkrtchyan +4 more
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Synthesis of 2-aryl-benzothiazoles via Ni-catalyzed coupling of benzothiazoles and aryl sulfamates
2-Aryl-benzothiazoles have been successfully synthesized via a simple coupling reaction between benzothiazoles and aryl sulfamates using a nickel catalyst. The nickel catalyst is inexpensive, reusable and commercially available.
Yu Xiaofeng +4 more
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