Results 111 to 120 of about 538,570 (408)

Expanding the palette of phenanthridinium cations [PDF]

open access: yes, 2014
5,6-Disubstituted phenanthridinium cations have a range of redox, fluorescence and biological properties. Some properties rely on phenanthridiniums intercalating into DNA, but the use of these cations as exomarkers for the reactive oxygen species (ROS ...
Acevedo   +114 more
core   +4 more sources

State‐of‐the‐Art, Insights, and Perspectives for MOFs‐Nanocomposites and MOF‐Derived (Nano)Materials

open access: yesAdvanced Materials, EarlyView.
Different approaches to MOF‐NP composite formation, such as ship‐in‐a‐bottle, bottle‐around‐the‐ship and in situ one‐step synthesis, are used. Owing to synergistic effects, the advantageous features of the components of the composites are beneficially combined, and their individual drawbacks are mitigated.
Stefanos Mourdikoudis   +6 more
wiley   +1 more source

Synthesis of 2H-azirine-2,2-dicarboxylic acids and their derivatives

open access: yesBeilstein Journal of Organic Chemistry
Methods for the preparation of 3-aryl-2H-azirine-2,2-dicarboxylic acids and their amides, esters, and azides by FeCl2-catalyzed isomerization of 3-aryl-5-chloroisoxazole-4-carbonyl chlorides into 3-aryl-2H-azirine-2,2-dicarbonyl dichlorides followed by ...
Anastasiya V. Agafonova   +2 more
doaj   +1 more source

(dme)MCl_3(NNPh_2) (dme= dimethoxyethane; M= Nb, Ta): A Versatile Synthon for [Ta═NNPh_2] Hydrazido(2-) Complexes [PDF]

open access: yes, 2010
Complexes (dme)TaCl_3(NNPh_2) (1) and (dme)NbCl_3(NNPh_2) (2) (dme =1,2-dimethoxyethane) were synthesized from MCl5 and diphenylhydrazine via a Lewis-acid assisted dehydrohalogenation reaction. Monomeric 1 has been characterized by X-ray, IR, UV−vis, ^(1)
Bercaw, John E., Tonks, Ian A.
core   +1 more source

Amine, Amido, and Imido Complexes of Tantalum Supported by a Pyridine-Linked Bis(phenolate) Pincer Ligand: Ta−N π-Bonding Influences Pincer Ligand Geometry [PDF]

open access: yes, 2009
A series of tantalum imido and amido complexes supported by a pyridine-linked bis(phenolate) ligand has been synthesized. Characterization of these complexes via X-ray crystallography reveals both C_s and C_2 binding modes of the bis(phenolate)pyridine ...
Bercaw, John E.   +3 more
core   +2 more sources

Acid/Base‐Responsive Circularly Polarized Luminescence Emitters with Configurationally Stable Nitrogen Stereogenic Centers

open access: yesAdvanced Materials, EarlyView.
Circularly Polarized Luminescence (CPL) emitters based on Tröger's base analogues bearing two peripheral fluorophores (anthracene, pyrene or 9,9‐dimethylfluorene) are prepared following a straightforward and versatile synthetic approach from common precursors.
Pablo García‐Cerezo   +11 more
wiley   +1 more source

Mechanical Anisotropy and Multiple Direction-Dependent Dirac States in the Synthesized Ag3C20 Monolayer [PDF]

open access: yesarXiv, 2022
Recently, a 2D orthorhombic silver-organic framework, Ag3C20 monolayer, was synthesized by assembling organic molecules linked with multiple aryl-metal bonds. Herein, via first-principles study, we demonstrate that owing to the unique bonding feature, Ag3C20 monolayer not only exhibits strong mechanical anisotropy, but also possesses various tunable ...
arxiv  

Iodine-Mediated Facile One-Pot Access to N-Aryl-2-benzoxazolamines

open access: yesSynOpen, 2020
Facile, iodine-mediated access to N-aryl-2-benzoxazolamines has been achieved in a one-pot manner under mild reaction conditions. Reaction of 2-aminophenols and aryl isothiocyanates afforded N-aryl-2-benzoxazolamines in the presence of molecular iodine ...
Haruna Nariki   +4 more
doaj   +1 more source

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction.

open access: yesJournal of the American Chemical Society, 2019
A robust and practical protocol for preparing alkyl aryl ethers has been developed, which relies on using two types of ligands to promote Cu-catalyzed alkoxylation of (hetero)aryl halides.
Zhixiang Chen   +4 more
semanticscholar   +1 more source

Carbon Fiber Reinforced Thermoplastics: From Materials to Manufacturing and Applications

open access: yesAdvanced Materials, EarlyView.
A contemporary and critical review on carbon fiber reinforced thermoplastics. The common thermoplastic and carbon fiber applied in the manufacture of carbon fiber reinforced thermoplastics are summarized, and the processing and postprocessing methods are reviewed, with emphasis on state‐of‐the‐art welding techniques.
Howard (Hao) Wang   +6 more
wiley   +1 more source

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