Imide arylation with aryl(TMP)iodonium tosylates [PDF]
Beilstein Journal of Organic Chemistry, 2018 Herein, we describe the synthesis of N-aryl phthalimides by metal-free coupling of potassium phthalimide with unsymmetrical aryl(TMP)iodonium tosylate salts.
Souradeep Basu +2 more
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CHIMIA, 2011 Macrocyclization methodologies allowing access to macrocycles having an endo aryl ether and an endo aryl–aryl bond, especially those based on an intramolecular SNAr reaction and the Suzuki-Miyaura reaction, are summarized.
Qian Wang, Jieping Zhu
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Photochemical (Hetero-)Arylation of Aryl Sulfonium Salts [PDF]
Organic Letters, 2021 Organic letters 23(16), 6232-6236 (2021).
Zhao, Yue +3 more
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Palladium-Catalyzed Esterification of Aryl Fluorosulfates with Aryl Formates
MoleculesAn efficient palladium-catalyzed carbonylation of aryl fluorosulfates with aryl formates for the facile synthesis of esters was developed. The cross-coupling reactions proceeded effectively in the presence of a palladium catalyst, phosphine ligand, and ...
Xue Chen +8 more
doaj +3 more sources
Reversible Dehalogenation in On‐Surface Aryl–Aryl Coupling [PDF]
Angewandte Chemie International Edition, 2020 AbstractIn the emerging field of on‐surface synthesis, dehalogenative aryl–aryl coupling is unarguably the most prominent tool for the fabrication of covalently bonded carbon‐based nanomaterials. Despite its importance, the reaction kinetics are still poorly understood.
José I. Urgel +10 more
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Aryl–Aryl Interactions in (Aryl‐Perhalogenated) 1,2‐Diaryldisilanes
Chemistry – A European Journal, 2020 AbstractThree 1,2‐diaryltetramethyldisilanes X5C6‐(SiMe2)2‐C6X5 with two C6H5, C6F5, or C6Cl5 groups were studied concerning the importance of London dispersion driven interactions between their aryl groups. They were prepared from 1,2‐dichlorotetramethyldisilane by salt elimination.
Marvin Linnemannstöns +5 more
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Efficient Copper-Catalyzed N-Arylation of Sulfoximines with Aryl Iodides and Aryl Bromides [PDF]
The Journal of Organic Chemistry, 2005 Two simple and inexpensive systems for copper-catalyzed N-arylations of sulfoximines with aryl bromides and aryl iodides have been developed. Using 10 mol % of a copper(I) salt in combination with 20 mol % of a 1,2-diamine and Cs2CO3 provides N-arylated sulfoximines in high yields. Various functional groups and heteroatoms are tolerated.
Joerg Sedelmeier, Carsten Bolm
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ChemInform Abstract: Palladium‐Catalyzed α‐Arylation of Aryl Nitromethanes. [PDF]
ChemInform, 2015 AbstractThe straightforward reaction tolerates various aryl and hetaryl substituents except ortho‐substituted aryl groups.
Kelsey F. VanGelder, Marisa C. Kozlowski
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Direct Introduction of a Dimesitylboryl Group Using Base-Mediated Substitution of Aryl Halides with Silyldimesitylborane [PDF]
, 2016 The first dimesitylboryl substitution of aryl halides with a silylborane bearing a dimesitylboryl group in the presence of alkali-metal alkoxides is described.
Albrecht +68 more
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High throughput synthesis of 2,5-substituted indoles using a titanium carbenoid bearing boronate functionality [PDF]
, 2008 A titanium benzylidene complex bearing a boronate group converted resin-bound esters into enol ethers. Suzuki cross-coupling with aryl iodides followed by cleavage with acid completed the solid-phase synthesis of 2,5-disubstituted N-Boc-indoles.
Hartley, R.C. +3 more
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