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Generation of Aryl Radicals from Aryl Halides: Rongalite-Promoted Transition-Metal-Free Arylation
The Journal of Organic Chemistry, 2019A new and practical method for the generation of aryl radicals from aryl halides is reported. Rongalite as a novel precursor of super electron donors was used to initiate a series of electron-catalyzed reactions under mild conditions. These transition-metal-free radical chain reactions enable the efficient formation of C-C, C-S, and C-P bonds through ...
Fazhi Yu +4 more
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Asian Journal of Organic Chemistry
AbstractA simple photoinduced radical borylation, phosphonation, sulfurization and selenization of various aryl iodides to construct the structurally diverse C‐B/P/S/Se bonds has been developed. Using HCO2Na as the reductant, a wide range of aryl iodides including the substituted iodobenzenes, heteroaromatic iodides, aromatic iodides derived from the ...
Juan Tang +6 more
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AbstractA simple photoinduced radical borylation, phosphonation, sulfurization and selenization of various aryl iodides to construct the structurally diverse C‐B/P/S/Se bonds has been developed. Using HCO2Na as the reductant, a wide range of aryl iodides including the substituted iodobenzenes, heteroaromatic iodides, aromatic iodides derived from the ...
Juan Tang +6 more
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Recent Development of Aryl Diazonium Chemistry for the Derivatization of Aromatic Compounds
Chemical Reviews, 2021Fanyang Mo, Di Qiu, Lei Zhang
exaly
Aryl Transfer Strategies Mediated by Photoinduced Electron Transfer
Chemical Reviews, 2022Anthony R Allen +2 more
exaly
Organic Letters
We have developed an efficient gold-catalyzed C-S cross-coupling of various silver-based thionucleophiles with aryl iodides. Our method offers a one-stop-shop solution for synthesizing diverse sulfur-containing aromatics, including aryl thiocyanic acids, aryl diethyldithiocarbamates, aryl sulfones, and aryl thiobenzoates. Our protocol gives moderate to
Hongyan Liu, Guifang Chen, Bo Xu
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We have developed an efficient gold-catalyzed C-S cross-coupling of various silver-based thionucleophiles with aryl iodides. Our method offers a one-stop-shop solution for synthesizing diverse sulfur-containing aromatics, including aryl thiocyanic acids, aryl diethyldithiocarbamates, aryl sulfones, and aryl thiobenzoates. Our protocol gives moderate to
Hongyan Liu, Guifang Chen, Bo Xu
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Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications
Chemical Reviews, 2020Rodolphe Jazzar +2 more
exaly
Contemporary methods for generation of aryl radicals
Chemical Society Reviews, 2021Nikita Kvasovs
exaly
[RhIIICp*]‐Catalyzed Dehydrogenative ArylAryl Bond Formation
Angewandte Chemie International Edition, 2012J. Wencel-Delord +3 more
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