Results 321 to 330 of about 538,570 (408)

Supramolecular Gels as Active Tools for Reaction Engineering

Angewandte Chemie, EarlyView.
The unique combination of environments within gels, self‐assembled from low‐molecular‐weight gelators, offers the ability to control reactivity in new ways, achieving unique reaction outcomes, leading to the emerging concept of supramolecular gels as nanoreactors. Smart chemical engineering methods enable the use of such gels to fabricate materials and
David K. Smith
wiley   +1 more source

A porous metal-organic framework (Pd-MOF) as an efficient and recyclable catalyst for the C-O cross-coupling reactions. [PDF]

Sci Rep
Kumar A, Naglah AM, Jain V, Ballal S, Sharma A, Abosaoda MK, Singh A, Krithiga T, Ray S, Doshi OP.   +9 more
europepmc   +1 more source

Late‐Stage Cross‐Electrophile Coupling of Arylthianthrenium Salts with (Hetero)aryl (Pseudo)halides via Palladium Catalysis

Angewandte Chemie, EarlyView.
By employing complex arylthianthrenium salts and readily available (hetero)aryl (pseudo)halides as starting materials, in conjunction with hypoboric acid as a reductant, structurally diverse (hetero)biaryl motifs can be rapidly synthesized via palladium‐catalyzed cross‐coupling reaction.
Yuanhao Xie, Li Zhang, Tobias Ritter
wiley   +1 more source

Synthesis of Dithioester Derivatives by Base-Mediated Fragmentation of 1,3-Dithiolanes. [PDF]

Org Lett
Pelit H, Sinmaz MA, Ildem OA, Mert Z, Turhan YE, Aydin E, Yilmaz SD, Mentese A, Yucel B.   +8 more
europepmc   +1 more source

Photokatalytische Hydrierung von Chinolinen zu 1,2,3,4‐Tetrahdyrochinolinen mit Wasser als Wasserstoffatomdonor

Angewandte Chemie, EarlyView.
Für die trans‐selektive Hydrierung von Chinolinen unter Verwendung von Wasser als Wasserstoffatomquelle wird ein sequentieller Prozess vorgestellt, der eine Hydrierung und eine anschließende Stereomutation kombiniert. Mechanistische Studien zeigen, dass die Hydrierung durch einen Kaskadenprozess abläuft, der eine initiale cis‐selektive ...
Jingjing Zhang, Nico Spreckelmeyer, Jessika Lammert, Maxim‐Aleksa Wiethoff, Matthew James Milner, Christian Mück‐Lichtenfeld, Armido Studer   +6 more
wiley   +1 more source

Intercepting an avoided α-iminol rearrangement with a Petasis reaction for the synthesis of 2,3-diaryl substituted indoles. [PDF]

Commun Chem
Zhu HM, Lei T, Liao ZX, Xiang JC, Wu AX.
europepmc   +1 more source

Pyrazine‐Embedded 2D Conjugated Metal–Organic Framework with Quasi‐Honeycomb Lattice for High‐Capacitance Lithium‐Ion Storage

Angewandte Chemie, EarlyView.
A Cu‐OHDDQP 2D conjugated metal–organic framework (2D c‐MOF) was synthesized possessing a unique quasi‐honeycomb topology, from a pyrazine‐fused, D2‐symmetric ligand. The achieved 2D c‐MOF electrode displayed a remarkable gravimetric capacitance up to 452 A g−1 for electrochemical lithium storage.
Xiangyu Li, Yangyang Feng, Shuai Fu, Tianrui Wu, Peng Liang, Xicheng Ma, Rashid Iqbal, Yuzhen Qian, Yandong Ma, Mischa Bonn, Hua Wang, Hongjie Dai, Jingcheng Hao, Renhao Dong   +13 more
wiley   +1 more source

Organophotoredox-Catalyzed Stereoselective Synthesis of Bicyclo[3.2.0]heptanes via [2+2] Photocycloaddition. [PDF]

Molecules
Benettin T, Resta S, Forni A, Raimondi L, Puglisi A, Rossi S.   +5 more
europepmc   +1 more source

Mitigating Molecular Aggregation in Drug Discovery With Predictive Insights From Explainable AI

Angewandte Chemie, EarlyView.
In this work, MEGAN, our explainable AI model, is applied to predict small colloidally aggregating molecules (SCAMs), a significant source of false positives in drug discovery. MEGAN provides interpretable predictions and proposes structurally similar, non‐aggregating alternative molecules.
Hunter Sturm, Jonas Teufel, Kaitlin A. Isfeld, Pascal Friederich, Rebecca L. Davis   +4 more
wiley   +1 more source

Heterobimetallic Complexes That Point to When Bond Dissociation Energies Deviate from Computational Expectations. [PDF]

J Am Chem Soc
Bissig R, Oeschger R, Chen P.
europepmc   +1 more source