Photocatalytic Generation of a Ground-State Electron Donor Through Water Activation. [PDF]
Wiethoff MA, Lezius L, Studer A.
europepmc +1 more source
The enantioselective epoxidation of naphthalenes into their corresponding arene oxides with aqueous hydrogen peroxide is described. The reaction combines dearomatization with installation of chemically versatile functionality in an enantioselective manner.
Najoua Choukairi Afailal+2 more
wiley +1 more source
Retraction: Aryl glyoxal: a prime synthetic equivalent for multicomponent reactions in the designing of oxygen heterocycles. [PDF]
Sheikh AR, Arif A, Khan MM.
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A cationic Ir(I)‐complex modified with the chiral diphosphine DM‐SEGPHOS mediates the enantioselective hydroalkylation of diverse α‐substituted styrenes with N‐aryl glycine derivatives. The products are readily advanced to β‐quaternary α‐amino acids that are inaccessible or cumbersome to access by other means. Abstract A cationic Ir(I)‐complex modified
Fenglin Hong+4 more
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Visible-Light-Mediated Synthesis of Anomeric <i>S</i>-Aryl Glycosides via Electron Donor-Acceptor Complex Using Thianthrenium Salts. [PDF]
Zhou Z+6 more
europepmc +1 more source
closo‐Carboranylanaloga von β‐Arylethylaminen: Direkte Synthese aus Alkenen mittels EnT‐Katalyse
Eine Strategie zur direkten Synthese von closo‐Carboranylanaloga medizinisch relevanter β‐Arylethylamine aus Alkenen wird vorgestellt. Die Reaktion basiert auf der erstmaligen Erzeugung von closo‐Carboranylradikalen mittels Energietransfer‐(EnT)‐Katalyse und ihren besonderen mechanistischen Merkmalen.
Fritz Paulus+8 more
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Visible-Light Photocatalysis for Sustainable Chromene Synthesis and Functionalization. [PDF]
Pérez-Ramos P+4 more
europepmc +1 more source
DNA Holliday junctions, or four‐way junctions (4WJs) are an attractive therapeutic target due to their prevalence in DNA replication and repair, and viral disease. Combining experimental and computational methods, we show that quadruple‐stranded dinuclear platinum metallo‐cages are an excellent size and shape match for the cavity of the 4WJ open ...
Samuel J. Dettmer+6 more
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Access to arynes from arenes <i>via</i> net dehydrogenation: scope, synthetic applications and mechanistic analysis. [PDF]
Roberts RA+4 more
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Ruthenium‐Katalysierte ortho‐Arylierung von Benzoesäuren mit Arylthianthreniumsalzen
Es wurde eine katalytische Ortho‐Arylierungsmethode entwickelt, mit der Arylthianthreniumsalze in Carboxylat‐funktionalisierte Biaryle umgewandelt werden können. Die Carboxylatgruppe kann in situ entfernt oder für eine weitere Derivatisierung verwendet werden.
Kaiping Wang+9 more
wiley +1 more source