Direct Introduction of a Dimesitylboryl Group Using Base-Mediated Substitution of Aryl Halides with Silyldimesitylborane [PDF]
, 2016 The first dimesitylboryl substitution of aryl halides with a silylborane bearing a dimesitylboryl group in the presence of alkali-metal alkoxides is described.
Albrecht +68 more
core +1 more source
High throughput synthesis of 2,5-substituted indoles using a titanium carbenoid bearing boronate functionality [PDF]
, 2008 A titanium benzylidene complex bearing a boronate group converted resin-bound esters into enol ethers. Suzuki cross-coupling with aryl iodides followed by cleavage with acid completed the solid-phase synthesis of 2,5-disubstituted N-Boc-indoles.
Hartley, R.C. +3 more
core +1 more source
Angewandte Chemie, 2019 A (terpy)Pd/NHC cooperative catalyzed umpolung 1,4-addition of aryl iodides to enals to generate various bioactive β,β-diaryl propanoate derivatives is described.
Wenjun Yang +5 more
semanticscholar +1 more source
Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides [PDF]
, 2019 A carbon nitride material can be combined with homogeneous nickel catalysts for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions.
Cavedon, Cristian +3 more
core +1 more source
Ni-Catalyzed Aryl Sulfide Synthesis through an Aryl Exchange Reaction.
Journal of the American Chemical Society, 2021 A Ni-catalyzed aryl sulfide synthesis through an aryl exchange reaction between aryl sulfides and a variety of aryl electrophiles was developed. By using 2-pyridyl sulfide as a sulfide donor, this reaction achieved the synthesis of aryl sulfides without ...
Ryota Isshiki +3 more
semanticscholar +1 more source
Direct acylation of aryl amines using dimethylformamide and dimethylacetamide as the acyl resources
Journal of Saudi Chemical Society, 2016 The treatment of aryl amines with dimethylformamide (DMF) and dimethylacetamide (DMA) in the presence of hydrochloric acid brings about efficient N-acylation to give the corresponding aryl formamides and aryl acetamides in acceptable to excellent yields.
Qing Zhang, Cui Chen
doaj +1 more source
Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules [PDF]
, 2004 Reaction of PhCH₂Mn(CO)₅ with l,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which were η⁴-coordinated to a Mn(CO)₃ group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed ...
Mace, Wade +3 more
core +2 more sources
The Ah receptor: adaptive metabolism, ligand diversity, and the xenokine model [PDF]
, 2020 Author Posting. © American Chemical Society, 2020. This is an open access article published under an ACS AuthorChoice License. The definitive version was published in Chemical Research in Toxicology, 33(4), (2020): 860-879, doi:10.1021/acs.chemrestox ...
Avilla, Mele N. +4 more
core +1 more source
Synthesis of Morphinans through Anodic Aryl‐Aryl Coupling
The Chemical Record, 2021 AbstractThe morphinans are an important class of structurally fascinating and physiologically important natural products as exemplified by the famous opium alkaloids of the morphine family. Although this class of secondary metabolites from the juice of the opium poppy capsule was already used for medicinal purposes thousands of years ago, chemical ...
Nina Vierengel +3 more
openaire +4 more sources
One-pot radioiodination of aryl amines via stable diazonium salts: preparation of 125I-imaging agents [PDF]
, 2017 An operationally simple, one-pot, two-step tandem procedure that allows the incorporation of radioactive iodine into aryl amines via stable diazonium salts is described.
Luthra, Sajinder K. +4 more
core +2 more sources