Results 41 to 50 of about 399,883 (354)

Palladium‐Catalyzed Direct Arylation of Aryl(azaaryl)methanes with Aryl Halides Providing Triarylmethanes. [PDF]

ChemInform, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Niwa, Takashi, Yorimitsu, Hideki, Oshima, Koichiro   +2 more
openaire   +4 more sources

Dihedral-Angle-Controlled Crossover from Static Hole Delocalization to Dynamic Hopping in Biaryl Cation Radicals [PDF]

, 2016
In cases of coherent charge-transfer mechanism in biaryl compounds the rates follow a squared cosine trend with varying dihedral angle. Herein we demonstrate using a series of biaryl cation radicals with varying dihedral angles that the hole ...
Bates, Benniston, Brunschwig, Cui, Hanss, Heckmann, Mishchenko, Mulliken, Rathore, Rathore, Rathore, Reed, Scholes, Shukla, Spettel, Talipov, Talipov, Talipov, Talipov, Talipov, Venkataraman, Vonlanthen, Weinhold, Zhai, Zhai   +24 more
core   +2 more sources

One-pot H/D exchange and low-coordinated iron electrocatalyzed deuteration of nitriles in D2O to α,β-deuterio aryl ethylamines

Nature Communications, 2022
One-pot efficient synthesis of α,β-deuterio aryl ethylamines with high deuterium ratios using an easy-to-handle deuterated source under ambient conditions is desirable.
Rui Li, Yongmeng Wu, Changhong Wang, Meng He, Cuibo Liu, Bin Zhang   +5 more
doaj   +1 more source

The structure of the agrochemical fungicidal 4-Chloro-3-(3,5-dichloropheny)-1H-pyrazole, RPA 406194 and related compounds [PDF]

, 2003
The difficulties to obtain convenient monocrystals of the important fungicide RPA 406194 have been overcome by a combination of solid state 13C NMR, X-ray powder diffraction and molecular modeling.
Abboud, Aguilar-Parrilla, Bennema, Berkovitch-Yellin, Burton, Cativiela, Cativiela, Claramunt, Dunitz, Elguero, Elguero, Eliel, Foces-Foces, Grimbergen, Harris, Hartman, Hartman, Hartman, Hartman, Jean Paul Canselier, Jean-Pierre Vors, José Elguero, Lin, Lin, Lommerse, López, Marı́a Luisa Jimeno, Minkin, Nadine Gabas, Nadine Jagerovic, Olivieri, Stothers, Vincent Gerbaud, Weissbuch, Winn, Winn   +35 more
core   +2 more sources

The synthesis of 3-aryl-3-trifluoromethyl-2,3-dihydro-1H-pyrrolizin-1-ones

Журнал органічної та фармацевтичної хімії, 2019
Aim. To develop the efficient method for the synthesis of 3-aryl-3-trifluoromethyl-2,3-dihydro-1H-pyrrolizin-1-ones as promising scaffolds in design of bioactive compounds. Results and discussion.
S. V. Melnykov, V. M. Tkachuk, A. M. Grozav, I. Gillaizeau, V. A. Sukach   +4 more
doaj   +1 more source

FeO(OH)@C‐Catalyzed Selective Hydrazine Substitution of p‐Nitro‐Aryl Fluorides and their Application for the Synthesis of Phthalazinones

ChemistryOpen, 2022
An efficient hydrazine substitution of p‐nitro‐aryl fluorides with hydrazine hydrates catalyzed by FeO(OH)@C nanoparticles is described. This hydrazine substitutions of p‐nitro‐aryl fluorides bearing electron‐withdrawing groups proceeded efficiently with
Dingzhong Li, Wensheng Zhang, Dr. Longzhi Zhu, Prof. Dr. Shuang‐Feng Yin, Prof. Dr. Nobuaki Kambe, Prof. Dr. Renhua Qiu   +5 more
doaj   +1 more source

An Efficient Synthesis of 1-Aryl-3-(indole-3-yl)-3-(2-aryl-1,2,3-triazol-4-yl)propan-1-one Catalyzed by a Brønsted Acid Ionic Liquid

Molecules, 2010
An efficient synthesis of novel 1-aryl-3-(indole-3-yl)-3-(2-aryl-1,2,3-triazol-4-yl)propan-1-ones from indoles and 1-aryl-3-(2-aryl-1,2,3-triazol-4-yl)propan-1-one using a Brønsted acid ionic liquid [Sbmim][HSO4] as catalyst is described.
Chuan-Ji Yu, Chen-Jiang Liu
doaj   +1 more source

Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond formation at palladium [PDF]

, 2010
This article describes the rational design of 1st generation systems for oxidatively-induced Aryl– CF3 bond-forming reductive elimination from PdII.
Gary, J. Brannon
core   +1 more source

Photoinitiated oxidative addition of CF3I to gold(I) and facile aryl-CF3 reductive elimination. [PDF]

, 2014
Herein we report the mechanism of oxidative addition of CF3I to Au(I), and remarkably fast Caryl-CF3 bond reductive elimination from Au(III) cations. CF3I undergoes a fast, formal oxidative addition to R3PAuR (R = Cy, R = 3,5-F2-C6H4, 4-F-C6H4, C6H5, 4 ...
TOSTE, F. Dean, Winston, Matthew, Wolf, William   +2 more
core   +1 more source

A general model for analysis of linear and hyperbolic enzyme inhibition mechanisms

FEBS Open Bio, EarlyView.
We developed a general enzyme kinetic model that integrates these six basic inhibition mechanism onto a single one. From this model, we deduced a general enzyme kinetic equation that through modulation of simple parameters, γ (the relative inhibitor affinity for two binding sites) and β (the reactivity of the enzyme–substrate–inhibitor complex), is ...
Rafael S. Chagas, Sandro R. Marana
wiley   +1 more source