Results 41 to 50 of about 538,570 (408)
Symurban Nanocrystals for Advanced Anti-Pollution Skincare [PDF]
Several of most common dermatoses worldwide, e.g., psoriasis and atopic dermatitis, are worsened in their clinical picture when the skin is regularly exposed to an increased air pollution level, e.g., particulate matter.
Köpke, Daniel, Pyo, Sung Min
core +1 more source
Boron Arylations of Subporphyrins with Aryl Zinc Reagents [PDF]
AbstractBoron arylations of B‐(methoxo)triphenylsubporphyrin have been developed with a combined use of ArZnI⋅LiCl and trimethylsilyl chloride. Aryl zinc reagents bearing bromo, cyano, amide, and ester groups can be employed for the B‐arylation reaction to provide the corresponding B‐arylated subporphyrins in moderate yields.
Kotani, Ryota+3 more
openaire +4 more sources
Surface enhanced infrared absorption spectroscopy for graphene functionalization on copper [PDF]
The monolayer form of CVD graphene is imposing crucial challenges in characterization of the targeted covalent functionalization due to the low amount of grafting moieties on the surface, which in turn hampers drawing conclusions about reactivity-properties relationships. Due to the growing interest in chemically modified graphene new, reliable and non-
arxiv +1 more source
An investigation on the effect of substituent at the 2-position of mono-substituted quinoxalines in the synthesis of di-substituted quinoxaline derivatives via nucleophilic substitution reactions, is reported.
Ndumiso Thamsanqa Ndlovu+1 more
doaj +1 more source
We describe a mechanism-guided discovery of a synthetic methodology that enables the preparation of aromatic amides from 2-bromo-2,2-difluoroacetamides utilizing a copper-catalyzed direct arylation.
Satenik Mkrtchyan+4 more
doaj +1 more source
Palladium-catalyzed acetylation of arenes. [PDF]
A simple method for the preparation of aryl methyl ketones is reported. The transformation involves the Pd-catalyzed coupling of an acyl anion equivalent, acetyltrimethylsilane, with aryl bromides to afford the corresponding acetylated arenes in ...
Garg, Neil K, Ramgren, Stephen D
core +1 more source
2-aminophenols containing electron-withdrawing groups from N-aryl hydroxylamines [PDF]
Reaction of substituted N-aryl hydroxylamines with methanesulfonyl chloride, p-toluenesulfonyl chloride, or trifluoromethanesulfonic anhydride under basic conditions leads to the rearranged 2-aminophenols (45-94%).
Cooper, Anthony W. J.+3 more
core +1 more source
Indacenodithiophene homopolymers via direct arylation: direct polycondensation versus polymer analogous reaction pathways [PDF]
Indacenodithiophene (IDT) based materials are emerging high performance conjugated polymers for use in efficient organic photovoltaics and transistors. However, their preparation generally suffers from long reaction sequences and is often accomplished using disadvantageous Stille couplings.
arxiv +1 more source
Computational Insights into Electronic Excitations, Spin-Orbit Coupling Effects, and Spin Decoherence in Cr(IV)-based Molecular Qubits [PDF]
The great success of point defects and dopants in semiconductors for quantum information processing has invigorated a search for molecules with analogous properties. Flexibility and tunability of desired properties in a large chemical space have great advantages over solid-state systems. The properties analogous to point defects were demonstrated in Cr(
arxiv +1 more source
Microwave-mediated synthesis of N-methyliminodiacetic acid (MIDA) boronates [PDF]
A library of over 20, mainly aryl or heteroaryl, N-methyliminodiacetic acid (MIDA) boronates have been synthesised. A rapid microwave-mediated (MW) method (5–10 min) has been developed using polyethylene glycol 300 (PEG 300) as solvent.
Close, Adam J+3 more
core +1 more source