Imide arylation with aryl(TMP)iodonium tosylates [PDF]
Beilstein Journal of Organic Chemistry, 2018 Herein, we describe the synthesis of N-aryl phthalimides by metal-free coupling of potassium phthalimide with unsymmetrical aryl(TMP)iodonium tosylate salts.
Souradeep Basu +2 more
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Z-Retentive Enantioselective Rh-Catalyzed Hydroarylation of E,Z-Dienes. [PDF]
Angew Chem Int Ed EnglThe Rh‐catalyzed hydroarylation of conjugated E,Z‐dienoates is found to proceed with high selectivity for addition to the E‐alkene unit. Mechanistic analysis of this Z‐retentive process points towards preferred binding of the E‐alkene unit to a Rh‐aryl species to give rise to the observed selectivity and that Rh‐enolate protonolysis to be turnover ...
McNutt W +4 more
europepmc +3 more sources
Benzyne arylation of oxathiane glycosyl donors [PDF]
Beilstein Journal of Organic Chemistry, 2010 The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in situ from 1-aminobenzotriazole (1-ABT) and lead tetraacetate.
Martin A. Fascione, W. Bruce Turnbull
doaj +2 more sources
Straightforward synthesis of N -arylindoles via one-pot Fischer indolisation–indole N -arylation
, 2023 A microwave-promoted, one-pot, three-component synthesis of N-arylindoles has been developed, utilising sequential Fischer indolisation then copper(I)-catalysed indole N-arylation.
M Lintott (21953192), A Perry (9857990)
core +4 more sources
Copper-Catalyzed Selective Arylation of Oxadiazolones by Diaryliodonium Salts [PDF]
, 2021 The direct N-arylation of cyclic amides can be considered a pivotal issue for modern organic chemistry. Here, we report the method for copper-catalyzed N-arylation of diverse oxadiazolones by diaryliodonium salts in mild conditions in high yields (up to ...
Pavel, Postnikov +8 more
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Reversible Dehalogenation in On‐Surface Aryl–Aryl Coupling [PDF]
Angewandte Chemie International Edition, 2020 AbstractIn the emerging field of on‐surface synthesis, dehalogenative aryl–aryl coupling is unarguably the most prominent tool for the fabrication of covalently bonded carbon‐based nanomaterials. Despite its importance, the reaction kinetics are still poorly understood.
Samuel Stolz +8 more
openaire +6 more sources
Photochemical (Hetero-)Arylation of Aryl Sulfonium Salts [PDF]
Organic Letters, 2021 Organic letters 23(16), 6232-6236 (2021).
Zhao, Yue +3 more
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Ligand-Free Ullmann-Type Arylation of Oxazolidinones by Diaryliodonium Salts [PDF]
, 2022 The arylation of azaheterocycles can be considered as one of the most important processes for the preparation of various biologically active compounds.
Natalia , Soldatova +7 more
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Aryl–Aryl Interactions in (Aryl‐Perhalogenated) 1,2‐Diaryldisilanes
Chemistry – A European Journal, 2020 AbstractThree 1,2‐diaryltetramethyldisilanes X5C6‐(SiMe2)2‐C6X5 with two C6H5, C6F5, or C6Cl5 groups were studied concerning the importance of London dispersion driven interactions between their aryl groups. They were prepared from 1,2‐dichlorotetramethyldisilane by salt elimination.
Marvin Linnemannstöns +5 more
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Reductive Arylation of Nitroarenes with Chloroarenes: Reducing Conditions Enable New Reactivity from Palladium Catalysts [PDF]
, 2023 Palladium-catalyzed C–N bond forming reactions are a key tool in modern synthetic organic chemistry. Despite advances in catalyst design enabling the use of a variety of aryl (pseudo)halides, the neces-sary aniline coupling partner is often synthesized ...
Daniel, Weix, Brett, Akana-Schneider
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