Results 91 to 100 of about 637,304 (300)

Abordagens em síntese assimétrica Approaches in asymmetric synthesis

open access: yesQuímica Nova, 1998
The approaches in asymmetric synthesis as the chiron approach, chiral auxiliaries, chiral reagents and asymmetric catalysis are described in a simplified way.
Sergio Pinheiro, Vítor F. Ferreira
doaj   +1 more source

Supramolecular self-assembled ligands in asymmetric transition metal catalysis

open access: yes, 2012
The design of novel chiral ligands is at the core of asymmetric catalysis. The catalytic characteristics of a transition metal catalyst such as activity, selectivity and stability can be fine-tuned by optimization of the steric and electronic properties ...
van der Vlugt, J.I.   +2 more
core   +1 more source

Network Topology Governs Photocatalytic Water Splitting in Organic Two‐Dimensional Crystals

open access: yesAdvanced Functional Materials, EarlyView.
Network topology in organic two‐dimensional crystals (O2DCs) dictates the photocatalytic water splitting performance. Kagome‐lattice O2DCs exhibit strong electron‐hole mass asymmetry, spatially separated carriers, and longer recombination lifetimes, exceeding rhombic isomers.
Preeti Bhauriyal, Thomas Heine
wiley   +1 more source

Chirally Functionalized Mesoporous Organosilicas for Chiral Separation and Asymmetric Catalysis

open access: yes, 2009
Chiral PMOs (with chiral functionality in the framework) opens up a new avenue for the synthesis of chiral material and may exhibit promising application potentials in the fields of chiral separation and asymmetric catalysis.
杨启华
core  

Electrochemical Pathways for Nitrate Conversion to Ammonia: From Environmental Challenges to Ammonia Economy

open access: yesAdvanced Functional Materials, EarlyView.
This perspective presents recent advances in electrocatalytic nitrate reduction, focusing on reaction mechanisms, catalyst design, and electrolyzer configurations. Key challenges in selectivity, stability, and practical wastewater treatment are highlighted, while future directions for advancing sustainable ammonia synthesis and nitrate remediation are ...
Xintong Li   +9 more
wiley   +1 more source

Asymmetric Ligands Derived from Carbohydrates [PDF]

open access: yes, 2011
This thesis describes the incorporation of carbohydrate groups in thiourea, 1, or iminophosphorane, 2, ligands. Several carbohydrate acyl thioureas, 3, were synthesised from the reaction of protected and unprotected D‐glucosamine with acyl ...
Jarman, Bevan Peter
core  

Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics

open access: yes, 2011
Catalytic asymmetric hydrogenations of prochiral unsaturated compounds, such as olefins, ketones, and imines, have been intensively studied and are considered as a versatile method of the synthesis of chiral compounds due to atom economy and operational ...
Xiang-Ping Hu   +10 more
core   +1 more source

Self‐Assembled Hybrid Cell‐Enzyme Materials for Gas‐Powered Biocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
Integrating living cells with programmable enzyme networks enables hybrid materials that convert gaseous feedstocks into chemical reducing power. These gas‐powered catalytic beads operate as modular, recyclable platforms for adaptive biocatalysis and sustainable synthesis.
Marius Stoeckle   +2 more
wiley   +1 more source

Advances in asymmetric organocatalysis over the last 10 years

open access: yesNature Communications, 2020
Organocatalysis has become a major pillar of (asymmetric) catalysis. Here, the authors discuss recent trends in organocatalytic activation modes for challenging stereoselective transformations and the emerging integration with other fields, such as ...
Shao-Hua Xiang, Bin Tan
doaj   +1 more source

Asymmetric catalysis in the nanocage of porous materials

open access: yes, 2012
Asymmetric catalysis in the nanocage of porous ...
杨启华, 李灿
core  

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