Results 131 to 140 of about 848,132 (406)

Rational design of a (S)-selective-transaminase for asymmetric synthesis of (1S)-1-(1,1′-biphenyl-2-yl)ethanamine [PDF]

, 2016
Amine transaminases offer an environmentally sustainable synthesis route for the production of pure chiral amines. However, their catalytic efficiency toward bulky ketone substrates is greatly limited by steric hindrance and therefore presents a great ...
Allen, Christopher C.R., Brown, Rodney T., Carvalho, Alexandra T.P., Caswell, Jill M., Dheeman, Dharmendra S., Dourado, Daniel F.A.R., Huang, Meilan, Kulakov, Leonid, Miskelly, Iain, Moody, Thomas S., Pohle, Stefan, Quinn, Derek J., Skvortsov, Timofey   +12 more
core   +3 more sources

Ultrafast Room‐Temperature Nanofabrication via Ozone‐Based Gas‐Phase Metal‐Assisted Chemical Etching for High‐Performance Silicon Photodetectors

Advanced Functional Materials, EarlyView.
Ozone‐based gas‐phase metal‐assisted chemical etching enables unprecedented room‐temperature fabrication of high‐quality silicon nanowires. The superior oxidation potential of O3 drives rapid vertical etching (1 µm min−1) while maintaining exceptional structural integrity. The pristine nanowire surfaces enable high‐performance core‐shell photodetectors
Hyein Cho, Yejin Han, Geonhwi Kim, Jihwan Jeong, Seongmin Lee, Yebin Ahn, Sang Beom Hong, Soohyeok Park, Inkyeong Park, So Eun Jang, Duck Hyun Youn, Han‐Don Um   +11 more
wiley   +1 more source

Insights Into the Carboxyltransferase Reaction of Pyruvate Carboxylase From the Structures of Bound Product and Intermediate Analogs [PDF]

, 2013
Pyruvate carboxylase (PC) is a biotin-dependent enzyme that catalyzes the MgATP- and bicarbonate-dependent carboxylation of pyruvate to oxaloacetate, an important anaplerotic reaction in central metabolism.
Lietzan, Adam D., Maurice, Martin St.
core   +2 more sources

Tuning D‐Band Center of Vanadium in Constructing Lattice‐Matched Coherent Heterostructure for Enhanced Sodium Storage

Advanced Functional Materials, EarlyView.
The coherent heterostructure and the strong stress field at the heterointerface upshift the d‐band center of vanadium toward the Fermi level, which effectively lowers the Na+ diffusion barrier, facilitates charge transfer and accelerates reaction kinetics.
Xuexia Song, Jingjing Wang, Qinting Jiang, Ming Li, Ruixian Duan, Jun Li, Wenbin Li, Wei Xiao, Gaini Zhang, Chong Xie, Xueliang Sun, Xifei Li   +11 more
wiley   +1 more source

Asymmetric reactions in continuous flow

Beilstein Journal of Organic Chemistry, 2009
An overview of asymmetric synthesis in continuous flow and microreactors is presented in this review. Applications of homogeneous and heterogeneous asymmetric catalysis as well as biocatalysis in flow are discussed.
Xiao Yin Mak, Paola Laurino, Peter H. Seeberger   +2 more
doaj   +1 more source

Atomic Size Misfit for Electrocatalytic Small Molecule Activation

Advanced Functional Materials, EarlyView.
This review explores the application and mechanisms of atomic size misfit in catalysis for small molecule activation, focusing on how structural defects and electronic properties can effectively lower the energy barriers of chemical bonds in molecules like H2O, CO2, and N2.
Ping Hong, Changfan Xu, Huaping Zhao, Yong Lei   +3 more
wiley   +1 more source

An Eight-Step Continuous-Flow Total Synthesis of Vitamin B1

Engineering
Vitamin B1 is widely applied in the healthcare and food industry as an antineuritic and antioxidant to maintain the normal functioning of nerve conduction, the heart, and the gastrointestinal tract.
Meifen Jiang, Minjie Liu, Weijian Li, Yingqi Xia, Fen-Er Chen   +4 more
doaj  

The supramolecular attitude of metal-salophen and metal-salen complexes [PDF]

, 2018
In this review we cover some aspects of metal-salophen and metal-salen complex chemistry related to their supramolecular attitude. We examined under the lens of the non-covalent interactions their potential to behave as building blocks for auto-assembled
Dalla Cort, Antonella, Leoni, Luca
core   +2 more sources

Copper‐based Materials for Photo and Electrocatalytic Process: Advancing Renewable Energy and Environmental Applications

Advanced Functional Materials, EarlyView.
Cu‐based catalysts as a cornerstone in advancing sustainable energy technologies are fully reviewed in this manuscript, highlighting their potential in photo‐ and electrocatalysis. It includes metallic copper, copper oxides, copper sulfides, copper halide perovskites, copper‐based metal–organic frameworks (MOFs), and covalent organic frameworks (COFs),
Jéssica C. de Almeida, Yanjie Wang, Thais A. Rodrigues, Paulo H. H. Nunes, Vagner R. de Mendonça, Paulo H. E. Falsetti, Leticia V. Savazi, Tao He, Alexandra V. Bardakova, Aida V. Rudakova, Jie Tian, Alexei V. Emeline, Osmando F. Lopes, Antonio Otavio T. Patrocínio, Jia Hong Pan, Caue Ribeiro, Detlef W. Bahnemann   +16 more
wiley   +1 more source

The stochastic behavior of a molecular switching circuit with feedback [PDF]

, 2007
Background: Using a statistical physics approach, we study the stochastic switching behavior of a model circuit of multisite phosphorylation and dephosphorylation with feedback. The circuit consists of a kinase and phosphatase acting on multiple sites of
David Krakauer, Eric Smith, Krishnamurthy, Supriya, Supriya Krishnamurthy, Walter Fontana   +4 more
core   +10 more sources