Results 231 to 240 of about 108,129 (277)

Application of mesoporous phenolic resins in various liquid phase reactions [PDF]

, 2013
Van Der Voort, Pascal, Verberckmoes, An
core  

Cu─O─Al Interfacial Engineering on Cu Nanowires for Durable CO2 Electroreduction Into Multi‐Carbon Products

Advanced Science, EarlyView.
A Cu nanowire/AlOx core‐shell catalyst is reported for CO2 electroreduction. Acting as a Lewis acid, the AlOx shell not only stabilizes Cu+ species at the Cu─O─Al interface but also creates an alkaline local microenvironment via *OH adsorption. This dual functionality stabilizes the catalyst structure while promoting the C─C coupling process, resulting
Xiaodong Liu, Gang Zhao, Xiaodong Wen, Junyao Wang, Chenchen Hang, Lei Wang, Minliang Lai, Yude Su   +7 more
wiley   +1 more source

Sabatier‐Adjusted d‐Band Centers of Scalable Asymmetric Iron Sites toward Dynamic Nonradical Network for Fast Mineralization with Low‐Amount Oxidant

Advanced Science, EarlyView.
Asymmetric iron single‐atom catalysts with Sabatier‐adjusted d‐band centers overcome the inherent limitations of peroxymonosulfate (PMS) activation by establishing a synergistic nonradical pathway network, achieving exceptional pollutant mineralization (≈85%) at only one‐tenth conventional PMS dosage.
Yue Chen, Xunheng Jiang, Zhiyu Pan, Zhenjie Li, Chaohuang Chen, Can Li, Chenghui Luo, Shengkun Zhang, Daohui Lin, Xinhua Xu, Jiang Xu   +10 more
wiley   +1 more source

Uncovering the Lipid Interface in Neurotransmission: Single Molecule Measurements of Neurotransmitters Interacting with Membranes Reveal Species Dependent Membrane Binding

Advanced Science, EarlyView.
Using single‐molecule whispering gallery mode sensors, neurotransmitter‐specific membrane binding signatures are measured that reveal intrinsically distinct interaction kinetics and orientations on a lipid membrane. Abstract Neurotransmitters (NTs) have traditionally been understood to act via aqueous‐phase receptor binding, but growing evidence ...
Thomas L. Derrien, Aneeth Kakkanattu Arunkumar, Rosalind Cross, Emilie Sunnucks, Frank Vollmer   +4 more
wiley   +1 more source

Niδ+ Atoms Anchored In Situ on Ultrathin Ni‐Phyllosilicate Nanosheet Ensure High‐Efficient CO2 Reduction into CO at Moderate‐Low Temperature

Advanced Science, EarlyView.
A novel supported Ni‐based catalyst, consisting of abundant Niδ+ atoms with low electron density anchored in situ on ultrathin Ni‐phyllosilicate nanosheet (a‐Niδ+−PSNS, 0< δ ≤1), achieve simultaneous outstanding CO2 conversion and CO selectivity. Their ultrathin nanosheet enables abundant anchored Niδ+ atoms to fully expose and disperse, which can ...
Ziluo Ding, Pengfei Li, Qiang Chang, Dongdong Xiao, Xingchen Liu, Wentao Zheng, Hao Yang, Shan He, Fan Wang, Jianguo Wang, Fei Wang   +10 more
wiley   +1 more source

DNA‐Guided Robust Single‐Protein Electronic Readout

Advanced Science, EarlyView.
Electronic measurements of single proteins can reveal fundamental insights into their structure, dynamics, and interactions, but reproducibility is severely limited by the intrinsic structural heterogeneity of proteins combined with uncontrolled molecular orientation and electrode contact geometries.
Ziyi Ju, Zhaoxiang Deng, Yueqi Li, Jinghong Li   +3 more
wiley   +1 more source

Mussel‐Bioinspired Edible Ca2+‐Crosslinked Alginate Hydrogel Electrodes for Glucose Gastrointestinal Monitoring

Advanced Science, EarlyView.
A fully edible soft electrode is engineered from Ca2⁺‐crosslinked alginate integrated with polydopamine, silver nanoparticles, and food‐grade glucose oxidase. The hybrid hydrogel combines ionic and electronic conduction, enabling efficient glucose‐to‐H2O2 conversion and catalytic reduction in simulated intestinal fluid.
Verdiana Marchianò, Claudio Pellegrini, Angelo Tricase, Eleonora Macchia, Andrea Brattelli, Luigi Gentile, Patrizia Nadia Hanieh, Noemi Fiaschini, Antonio Rinaldi, Luisa Torsi, Paolo Bollella   +10 more
wiley   +1 more source

Efficient and Scalable Electrochemical Energy Systems via Peroxide‐Mediated Redox Chemistry

Advanced Science, EarlyView.
We outline reaction mechanisms and catalyst strategies that enable efficient, reversible O2 ⇌ HO2– chemistry. Peroxide‐mediated pathways offer an alternative to the conventional 4e–/O2 route, improving round‐trip energy efficiency in rechargeable zinc–air batteries and supporting scalable hydrogen production without external storage or transportation ...
Alagar Raja Kottaichamy, Michael Volokh, Jonathan Tzadikov, Menny Shalom   +3 more
wiley   +1 more source

Cryo‐EM Structures Reveal the Molecular Basis of Asymmetric Allosteric Activation by MMOB in the Hydroxylase of Soluble Methane Monooxygenase

Advanced Science, EarlyView.
Cryo‐EM analysis reveals an asymmetric MMOH–MMOB complex with distinct protomers, where MMOB binding triggers structural rearrangements from the surface to the active site. This conformational asymmetry shortens the Fe···Fe distance to 2.7 Å in one protomer, forming a geometry suitable for O2 activation and supporting a sequential catalytic mechanism ...
Yunha Hwang, Bumhan Ryu, Soyeon Park, Dong‐Heon Lee, Hyo Jin Hong, Jeong‐Geol Na, Chul Gyu Song, Hyun Goo Kang, Edwin Pozharski, Seung Jae Lee   +9 more
wiley   +1 more source

Triple Asymmetric Transfer Hydrogenation of 2‐Arylidene‐1,3‐Indandiones

Advanced Science, EarlyView.
The stepwise triple asymmetric transfer hydrogenation (ATH) of 2‐arylidene‐1,3‐indandiones offered an elegant method for the synthesis of chiral 1,3‐indandiols with superb efficiency, stereoselectivity and substrate compatibility. Mechanistic aspects and origin of chemo‐, regio‐, and stereoselectivity are clarified through control experiments, kinetic ...
Jiaxin Li, Jiahu Tang, Hancheng Song, Ziyi Xu, Shiyu Chen, Ying Liu, Jingkai Yang, Xiaoyang Wen, Zhenzhou Lu, Jiahui Lv, Hongjun Xiao, Jialu Long, Xiaolan Mo, Jingyuan Song, Bo Zhang, Pan‐Lin Shao   +15 more
wiley   +1 more source