Primary amine thioureas in asymmetric organocatalysis
This thesis focuses on primary amine thiourea organocatalysis. The Michael addition reaction of acetone to nitrostyrene catalyzed by primary amine thioureas (PAT) was studied in detail. The synergistic effects of multiple additives (water and acetic acid) in this reaction were determined by 1H NMR spectroscopic analysis.
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A combined continuous microflow photochemistry and asymmetric organocatalysis approach for the enantioselective synthesis of tetrahydroquinolines. [PDF]
Sugiono E, Rueping M.
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Synthesis of chiral sulfoximine-based thioureas and their application in asymmetric organocatalysis. [PDF]
Frings M, Thomé I, Bolm C.
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Asymmetric Counteranion-Directed Halogen Bonding Catalysis. [PDF]
Reinhard DL+6 more
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Organocatalytic Asymmetric Synthesis of Azabicyclo[2.1.1]hexanes. [PDF]
Alama L+4 more
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Novel asymmetric transformations under covalent organocatalysis
La aminocatálisis se ha convertido en un área de gran interés especialmente para el desarrollo de reacciones químicas estereocontroladas. Esta metodología implica la condensación de aminas primarias o secundarias quirales con aldehídos o cetonas, generando cantidades subestequiométricas de intermedios tipo azometino activados (enamina o ion iminio ...
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Organocatalyzed Enantioselective C-N Bond-Forming S<sub>N</sub>Ar Reactions for Synthesizing Stereogenic-at-Boron BODIPYs. [PDF]
Meng YD+10 more
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Recent Advances in the Enantioselective Organocatalytic [4+2] Cycloadditions. [PDF]
Bauer T.
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Copper(I)-Catalyzed Asymmetric α-Selenenylation of 2-Acylimidazoles. [PDF]
Tian H, Huang X, Xiao JZ, Yin L.
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Carbene-catalyzed enantioselective construction of a quasi-symmetrical spirocyclic hydroquinone with a minor chiral distinction. [PDF]
Ren P, Zhao Q, Chi YR, Zhu T.
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