Summary: Biomimetic catalysts have drawn broad research interest owing to both high specificity and excellent catalytic activity. Herein, we report a series of biomimetic catalysts by the integration of biomolecules (hemin or ferrous phthalocyanine) onto
Longlong Fan +7 more
doaj +1 more source
High resolution scanning tunneling spectroscopy of ultrathin Pb on Si(111)-(6x6) substrate
The electronic structure of Si(111)-(6x6)Au surface covered with submonolayer amount of Pb is investigated using scanning tunneling spectroscopy. Already in small islands of Pb with thickness of 1 ML Pb$_{(111)}$ and with the diameter of only about 2 nm ...
Altfeder +18 more
core +1 more source
Carbamazepine on a carbamazepine monolayer forms unique 1D supramolecular assemblies [PDF]
High-resolution STM imaging of the structures formed by carbamazepine molecules adsorbed onto a pseudo-ordered carbamazepine monolayer on Au(111) shows the formation of previously unreported 1-dimensional supramolecular ...
Florence, Alastair J +4 more
core +1 more source
Disordered but rhythmic—the role of intrinsic protein disorder in eukaryotic circadian timing
Unstructured domains known as intrinsically disordered regions (IDRs) are present in nearly every part of the eukaryotic core circadian oscillator. IDRs enable many diverse inter‐ and intramolecular interactions that support clock function. IDR conformations are highly tunable by post‐translational modifications and environmental conditions, which ...
Emery T. Usher, Jacqueline F. Pelham
wiley +1 more source
Orientation Selection of Supported Au Nanoparticles on (111)- and (001)-Terminated SrTiO3 Substrates
Orientation-dependent performance has been demonstrated in different materials consisting of nanoparticles on substrates. The fabrication of desirably oriented nanoparticles requires knowledge of orientation selection rules.
Wangwang Kuang, Guozhen Zhu
doaj +1 more source
Role of surface states in STM spectroscopy of (111) metal surfaces with Kondo adsorbates
A nearly-free-electron (NFE) model to describe STM spectroscopy of (111) metal surfaces with Kondo impurities is presented. Surface states are found to play an important role giving a larger contribution to the conductance in the case of Cu(111) and Au ...
J. Kondo +3 more
core +1 more source
Noncovalent Dimerization after Enediyne Cyclization on Au(111) [PDF]
We investigate the thermally-induced cyclization of 1,2 - bis(2 - phenylethynyl)benzene on Au(111) using scanning tunneling microscopy and computer simulations. Cyclization of sterically hindered enediynes is known to proceed via two competing mechanisms in solution: a classic C1 - C6 or a C1 - C5 cyclization pathway.
de Oteyza, Dimas G +9 more
openaire +8 more sources
PICALM::MLLT10 translocated leukemia
This comprehensive review of PICALM::MLLT10 translocated acute leukemia provides an in‐depth review of the structure and function of CALM, AF10, and the fusion oncoprotein (1). The multifaceted molecular mechanisms of oncogenesis, including nucleocytoplasmic shuttling (2), epigenetic modifications (3), and disruption of endocytosis (4), are then ...
John M. Cullen +7 more
wiley +1 more source
Role of d orbitals in the Rashba-type spin splitting for noble-metal surfaces
We investigate the Rashba-type spin splitting in the Shockley surface states on Au(111) and Ag(111) surfaces, based on first-principles calculations. By turning on and off spin-orbit interaction (SOI) partly, we show that although the surface states are ...
Choi, Hyoung Joon, Lee, Hyungjun
core +1 more source
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source

