In Situ Scanning Tunneling Microscopy Study of 5,6-Dimethyl Uracil on Au (111)
The hydrogen evolution mediated 5,6-dimethyluracil (5,6-DMU) film disordering and subsequent reordering was studied in situ in sulfuric acid solution on Au (111) using STM and cyclic voltammetry.
Cunha Frederico G. C., Nart Francisco C.
doaj
Adsorption of 5-Fluorouracil on Au(111) and Cu(111) surfaces
The adsorption of 5-Fluorouracil (5FU) on Au(111) and Cu(111) surfaces as a function of molecular coverage and temperature has been studied, using x-ray photoelectron spectroscopy (XPS) and near-edge x-ray absorption fine structure (NEXAFS) spectroscopy.
Andrew Cassidy +5 more
doaj +1 more source
Design and analysis strategies for robust microbiome ageing research
The gut microbiome changes with age and associates with age‐related morbidity and mortality, establishing it as a potential biomarker and intervention target for ageing. Realising this potential requires methodological rigour, yet distinguishing biological signals from methodological artefacts remains challenging across cohorts. This review provides an
Mark Olenik +5 more
wiley +1 more source
СТМ-дослідження впорядкування молекул діарилетенів на поверхні Аu(111)
З використанням скануючої тунельної мікроскопії (СТМ) досліджено процес самовпорядкування терфенілтіазол-похідних діарилетенів на поверхні Au(111).
S. V. Snegir +3 more
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Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
The formation of a binary porphyrinic self-assembled system between meso-tetrakis(4-carboxyphenyl) porphyrin (TCPP) and meso-tetrakis(4-dimethyl amino) porphyrin (TDAP) was easily designed through non-covalent interactions in solution and adsorbed on a ...
Esteban Sánchez-Muñoz +4 more
doaj +1 more source
Enhanced Superconductivity and Rashba Effect in a Buckled Plumbene‐Au Kagome Superstructure
Plumbene, with a structure similar to graphene, is expected to possess a strong spin–orbit coupling and thus enhances its superconducting critical temperature (Tc).
Wan‐Hsin Chen +17 more
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Reconstructing enzyme evolution by protein engineering
Natural enzyme evolution can be retraced by protein engineering methods such as directed evolution, rational design, and ancestral sequence reconstruction. These approaches reveal how enzymes emerged from ligand‐binding scaffolds, developed varying substrate preferences, formed oligomeric complexes, adapted to environmental changes, and evolved novel ...
Lukas Drexler +2 more
wiley +1 more source
Stable Au–C bonds to the substrate for fullerene-based nanostructures
We report on the formation of fullerene-derived nanostructures on Au(111) at room temperature and under UHV conditions. After low-energy ion sputtering of fullerene films deposited on Au(111), bright spots appear at the herringbone corner sites when ...
Taras Chutora +5 more
doaj +1 more source
Ethanol Oxidation on Pd/Au(111) Bimetallic Surfaces in Alkaline Solution
Catalytic properties of Pd/Au(111) nanostructures obtained by spontaneous palladium deposition using PdSO4 and PdCl2 salts were examined for the oxidation of ethanol in alkaline media. Atomic force microscopy has shown that counter anions in Pd salts are
Milutin Smiljanić +2 more
doaj +1 more source
Microbiome‐blood–brain barrier interactions in aging — mechanisms and therapeutic potential
Aging reshapes the gut microbiome (↓SCFA‐producing commensals; ↑pro‐inflammatory outputs), shifting circulating metabolites (↓SCFAs; ↑LPS, ↑TMAO, ↑PAA) that act at the BBB to increase nonspecific transcytosis, alter transport, and promote astrocyte reactivity, heightening brain vulnerability.
Daniel Cuervo‐Zanatta +3 more
wiley +1 more source

