Results 81 to 90 of about 31,584 (223)
Triggering autocatalytic reaction by host–guest interactions
Chemical Communications, 2016 The acceleration of a sequential reaction through electrostatic alteration of substrate basicity within a supramolecular host is demonstrated.
Volodymyr, Sashuk +3 more
openaire +3 more sources
Chemistry – A European Journal, EarlyView.Glycerol ethoxylate (GEO), a branched ethylene glycol derivative, both toughens commercial PLLA and accelerates its chemical recycling to L‐lactide. The lead sample, containing 10 wt.% GEO, shows 9x higher elongation at break and 6x higher tensile toughness than pure PLLA. The GEO–PLLA samples are efficiently chemically recycled to L‐lactide, even when
Madeleine L. Smith +4 more
wiley +1 more source
International Journal of Polymer Science, 2021 In the present research, the effect of Zn2Al layered double hydroxides (LDH) and nickel (II)-EDTA complex intercalated LDH (LDH-[Ni(EDTA)]-2) on the cure kinetics of glass fiber/epoxy prepreg (GEP) was explored using nonisothermal differential scanning ...
Reza Darvishi +2 more
doaj +1 more source
Self‐Immolative Gels: Programmable Degradation Using Self‐Immolative Linkers and Polymers
Chemistry – A European Journal, EarlyView.Self‐immolative linkers and polymers undergo bond‐cleaving reaction cascades in response to specific stimuli. Their incorporation into gels can be harnessed to release cargo, induce property changes, or trigger degradation in a highly controlled manner. These functions can be employed in applications such as sensing and drug delivery.
Chuanfeng Li, Elizabeth R. Gillies
wiley +1 more source
Density fingering of an exothermic autocatalytic reaction
Physical Review E, 2003 Density fingering of exothermic autocatalytic fronts in vertically oriented porous media and Hele-Shaw cells is studied theoretically for chemical reactions where the solutal and thermal contribution to density changes have opposite signs. The competition between these two effects leads to thermal plumes for ascending fronts.
Bánsági Jr. Tamás +5 more
openaire +3 more sources
The Asymmetric Self‐Replicative Alkylation of N‐Arylaldimines Using Organolithium Reagents
Chemistry – A European Journal, EarlyView.Here, we report a new asymmetric autoinductive reaction; the addition of nBuLi to N‐arylaldimines to form chiral lithium amides. The reaction proceeds with full conversion and complete transfer of chirality, representing the first example of an asymmetric autoinductive reaction with organolithium reagents.
Anka Hagelschuer +2 more
wiley +1 more source
Recent Advances in the Laser‐Based Fabrication and Applications of High‐Entropy Alloy Nanoparticles
MetalMat, EarlyView.This review presents recent advances in the laser‐based fabrication of high‐entropy alloy nanoparticles, focusing on scalable, environmentally friendly, and compositionally tunable synthesis methods. It highlights the critical influence of laser parameters on nanoparticle size, phase, and morphology, enabling tailored properties for applications in ...
Bibek Kumar Singh +4 more
wiley +1 more source
Machine Learning Assisted Prediction of Degradation Behavior of Poly(Lactic‐Co‐Glycolic Acid)
Materials Genome Engineering Advances, EarlyView.Using a gradient boosting‐based machine learning model trained on 484 data points, this study predicts the degradation behavior of poly(lactic‐co‐glycolic acid) (PLGA) implants. Degradation time, molecular weight, and lactide/glycolide ratio were identified as key governing factors, enabling accurate prediction while reducing reliance on extensive ...
Shuai Wang +11 more
wiley +1 more source
A molecular approach to complex adaptive systems [PDF]
, 2007 Complex Adaptive Systems (CAS) are dynamical networks of interacting agents which as a whole determine the behavior, adaptivity and cognitive ability of the system. CAS are ubiquitous and occur in a variety of natural and artificial systems (e.g., cells,
Decraene, James +2 more
core
Accelerated Degradation of PLA‐Based Composites in Harsh Alkaline Environment
Polymer Composites, EarlyView.Evolution of surface properties and features of RP sample treated in harsh conditions: FTIR and wetting analysis. ABSTRACT The performance of poly(lactic acid) (PLA) bioplastics under harsh service conditions must be understood to enable their use in multi‐use products.
Cristina Moliner +5 more
wiley +1 more source