Results 41 to 50 of about 3,581 (133)
Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner +4 more
wiley +1 more source
PdII‐Mediated Oxidative Amination for Access to a 9‐Azabicyclo[4.2.1]nonane Compound Library and Anatoxin‐a [PDF]
Intramolecular oxidative amination of readily accessible aminocyclooct‐4‐enes provides rapid and regioselective access to the 9‐azabicyclo[4.2.1]nonane framework characteristic of the natural product anatoxin‐a (1). This has enabled the synthesis of sp3‐rich chemical scaffolds suitable for diversification.
Dawood +12 more
openaire +1 more source
The absorption spectra of amoxicillin degradation by colloidal MnO2 in the presence and absence of surfactants. Herein, the oxidative degradation of amoxicillin (AMX) by water‐soluble colloidal MnO2 is investigated spectrophotometrically at 298 K in both uncatalyzed and nonionic micellar‐catalyzed media (Triton X‐100 and Brij‐35).
Neelam Sen +4 more
wiley +1 more source
Recent Advances in Bioconjugation of Aromatic Amino Acid Residues by a Reactivity‐Guided Approach
This review highlights recent advances in the bioconjugation of aromatic amino acids residues, focusing on strategies that leverage their inherent chemical reactivity to enable precise and versatile modifications of biomacromolecules, illustrating relevant applications.
Bruno M. da S. Santos +3 more
wiley +1 more source
2 pages, 1 table, 1 scheme. The amidyl radical intermediates, produced by photolysis of medium-sized lactams 7-heptanelactam (1), 8-octanelactam (3), and 9-nonanelactam (6) in the presence of (diacetoxyiodo)benzene (DIB) and iodine, undergo transannular hydrogen abstraction to afford intermolecularly functionalised compounds such as oxoindolizidines (4)
Dorta, Rosa L. +2 more
openaire +2 more sources
Reductive amido bond cleavage reaction, previously elaborated by our laboratory for the synthesis of carbocyclic ribothymidine from readily available 2-azabicyclo[2.2.1]hept-5-en-3-one, was successfully applied to the synthesis of carbocyclic analogues of thymidine and related compounds.
Nobuya KATAGIRI +3 more
openaire +2 more sources
Monoester of benzylmalonic acid (I) and 3-carboxy-4-octahydroquinolizinone (V) were coupled with benzenediazonium salt to yield labile phenylhydrazones, Iia and VII, respectively. IIa was kept standing in chloroform or heated to give another phenylhydrazone (IIb). VIa was similarly converted into VIb.
YOSHIO ARATA +2 more
openaire +2 more sources
Studies on 1-Azabicyclo Compounds. XXIII. Mercuric Acetate Oxidation of Deoxynupharidine
YOSHIO ARATA +2 more
openaire +2 more sources
Studies on 1-Azabicyclo Compounds. (4). : Synthesis of 4-Substituted Octahydroisoquinolizines
Y, Arata, K, Sakai, T, Asai, M, Tsukioka
openaire +3 more sources

