Results 41 to 50 of about 3,581 (133)

Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 4, 17 February 2026.
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner   +4 more
wiley   +1 more source

PdII‐Mediated Oxidative Amination for Access to a 9‐Azabicyclo[4.2.1]nonane Compound Library and Anatoxin‐a [PDF]

open access: yesEuropean Journal of Organic Chemistry, 2018
Intramolecular oxidative amination of readily accessible aminocyclooct‐4‐enes provides rapid and regioselective access to the 9‐azabicyclo[4.2.1]nonane framework characteristic of the natural product anatoxin‐a (1). This has enabled the synthesis of sp3‐rich chemical scaffolds suitable for diversification.
Dawood   +12 more
openaire   +1 more source

Study of Uncatalyzed and Micellar‐Catalyzed Oxidative Degradation of Amoxicillin by Colloidal MnO2: Experimental Optimization and Mechanistic Aspects

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 5, 7 February 2026.
The absorption spectra of amoxicillin degradation by colloidal MnO2 in the presence and absence of surfactants. Herein, the oxidative degradation of amoxicillin (AMX) by water‐soluble colloidal MnO2 is investigated spectrophotometrically at 298 K in both uncatalyzed and nonionic micellar‐catalyzed media (Triton X‐100 and Brij‐35).
Neelam Sen   +4 more
wiley   +1 more source

Recent Advances in Bioconjugation of Aromatic Amino Acid Residues by a Reactivity‐Guided Approach

open access: yesThe Chemical Record, Volume 26, Issue 2, February 2026.
This review highlights recent advances in the bioconjugation of aromatic amino acids residues, focusing on strategies that leverage their inherent chemical reactivity to enable precise and versatile modifications of biomacromolecules, illustrating relevant applications.
Bruno M. da S. Santos   +3 more
wiley   +1 more source

Hypervalent organoiodine reagents in the transannular functionalisation of medium-sized lactams: synthesis of 1-azabicyclo compounds

open access: yesJ. Chem. Soc., Chem. Commun., 1989
2 pages, 1 table, 1 scheme. The amidyl radical intermediates, produced by photolysis of medium-sized lactams 7-heptanelactam (1), 8-octanelactam (3), and 9-nonanelactam (6) in the presence of (diacetoxyiodo)benzene (DIB) and iodine, undergo transannular hydrogen abstraction to afford intermolecularly functionalised compounds such as oxoindolizidines (4)
Dorta, Rosa L.   +2 more
openaire   +2 more sources

Synthesis of Nucleosides and Related Compounds. XXII. Carbocyclic Analogues of Thymidine and Related Compounds from 2-Azabicyclo(2.2.1)hept-5-en-3-ones.

open access: yesChemical and Pharmaceutical Bulletin, 1991
Reductive amido bond cleavage reaction, previously elaborated by our laboratory for the synthesis of carbocyclic ribothymidine from readily available 2-azabicyclo[2.2.1]hept-5-en-3-one, was successfully applied to the synthesis of carbocyclic analogues of thymidine and related compounds.
Nobuya KATAGIRI   +3 more
openaire   +2 more sources

Studies on 1-Azabicyclo Compounds. XII. Synthesis of 5, 6, 8, 9, 10, 11, 11a, 12-Octahydroindolo [3, 2-b] quinolizine and Related Compounds

open access: yesChemical and Pharmaceutical Bulletin, 1972
Monoester of benzylmalonic acid (I) and 3-carboxy-4-octahydroquinolizinone (V) were coupled with benzenediazonium salt to yield labile phenylhydrazones, Iia and VII, respectively. IIa was kept standing in chloroform or heated to give another phenylhydrazone (IIb). VIa was similarly converted into VIb.
YOSHIO ARATA   +2 more
openaire   +2 more sources

Studies on 1-azabicyclo compounds. XXII. Stereochemistry of 9a-substituted quinolizidine methiodides.

open access: yesChemical and Pharmaceutical Bulletin, 1975
YOSHIO ARATA   +3 more
openaire   +2 more sources

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